Electrosorption enhanced electrooxidation of a model organic pollutant at 3D SnO2-Sb electrode in superimposed pulse current mode.

Abstract:

:In this work, the novel pulse "electrosorption-electrooxidation-electrosorption" (PESO) mode is developed in the superimposed pulse current system for benzoic acid oxidation. Due to the synergistic effect of electrosorption and electrooxidation at TiO2-NTs/3D-SnO2-Sb electrode in PESO mode, the enhancement of removal efficiency, improvement in mass transport and decrease of energy consumption were significantly obvious. The mechanism for the great enhancement of the mode is analyzed in details. The strengthened interaction between electrode and organics, increased instantaneous currents and lower intermediate accumulation contributed to the significant enhancement of electrochemical performance of the superimposed pulse system. The pulse PESO mode was an efficient and promising method for treating organic pollutants.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Chen Y,Tu Y,Bai Y,Li J,Lu J

doi

10.1016/j.chemosphere.2017.12.074

subject

Has Abstract

pub_date

2018-03-01 00:00:00

pages

63-69

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(17)32044-1

journal_volume

195

pub_type

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