Abstract:
:Naphthols are industrial contaminants occurring widely in soils and waters. Remediation of organic pollutants can be done by chemical oxidation using persulfate. However, most research experiments testing degradation of organic pollutants have been done in ideal conditions, e.g. using a pure compound in pure water, and thus are weakly representative of real natural conditions where pollutants occur in complex mixtures of numerous organic compounds. Therefore we tested here the effect of the presence of small organic acids, as typical compounds occurring in natural media, on the degradation of 1-napthol with persulfate and iron oxides. Results show that organic acids decreased naphthol transformation by 3.7% for malic acid, 53.2% for tartaric acid, 72.3% for citric acid and 77% for oxalic acids, in a magnetite/persulfate system during 10 h. Meanwhile, the dissolved Fe species increased gradually with the reaction time; the highest concentration of Fe ions reached to ∼18 μM L-1 in aqueous phase. Electron paramagnetic resonance technique was applied to determine reactive oxygen species (ROS). The spin density of ·OH, detected as the main ROS, decreased initially, followed by gradually increase, suggesting that organic acids might inhibit the degradation of 1-naphthol by competing with ·OH. These findings disclose the high inhibition of the transformation by organic acids, and thus, more generally, imply that studies using only pure contaminants are weakly representative for remediation of real, natural samples.
journal_name
Chemospherejournal_title
Chemosphereauthors
Huang D,Wang T,Zhu K,Zhao S,Shi Y,Ye M,Wang C,Jia Hdoi
10.1016/j.chemosphere.2019.02.127subject
Has Abstractpub_date
2019-06-01 00:00:00pages
1-8eissn
0045-6535issn
1879-1298pii
S0045-6535(19)30351-0journal_volume
225pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::This study aimed to reveal the baseline of natural variations in antibiotic resistance genes (ARGs) in soil without anthropogenic activities over the decades. Nine soil samples with different time of soil formation were taken from the Yancheng Wetland National Nature Reserve, China. ARGs and mobile genetic elements (M...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128985
更新日期:2021-03-01 00:00:00
abstract::Remediation of polluted groundwater often requires oxygen delivery into subsurface to sustain aerobic bacteria. Air sparging or injection of oxygen containing solutions (e.g., hydrogen peroxide) into the subsurface are common. In this study visible light was delivered into the subsurface using radially emitting optica...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.12.089
更新日期:2018-03-01 00:00:00
abstract::Carbon Nanotubes (CNTs) and nano Zero-Valent Iron (nZVI) particles, as well as two nanocomposites based on these novel nanomaterials, were employed as nano-adsorbents for the removal of hexavalent chromium, selenium and cobalt, from aqueous solutions. Nanomaterials characterization included the determination of their ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.03.032
更新日期:2018-06-01 00:00:00
abstract::Glyphosate is an herbicide used widely and increasingly since the early 1990s in production of many crops and in urban areas. However, knowledge on the transport of glyphosate and its degradation to aminomethylphosphonic acid (AMPA) in ecosystems receiving urban or agricultural runoff is lacking. Here we show that tra...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.04.054
更新日期:2013-01-01 00:00:00
abstract::Refined fuels have considerable share of pollution of marine ecosystems. Gasoline is one of the most consumed fuel worldwide, but its effects on marine benthic primary producers are poorly investigated. In this study, Ulva lactuca was chosen as a biological model due to its cosmopolitan nature and tolerance to high le...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.04.126
更新日期:2016-08-01 00:00:00
abstract::Photochemical decomposition of a fluorotelomer unsaturated carboxylic acid, C3F7CFCHCOOH (1), in the presence of WO3 and an electron acceptor (S2O8(2-) or H2O2) in water under visible-light irradiation was investigated. Under an O2 atmosphere, 1 was not decomposed either by TiO2 (P25) or WO3 alone. A combination of WO...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.09.024
更新日期:2013-11-01 00:00:00
abstract::Biochemical and genetic studies of xenobiotic metabolism in the model plant Arabidopsis have significant potential in providing information for phytoremediation. This paper presents the toxicity of 2,6-dinitrotoluene (2,6-DNT) to Arabidopsis under axenic conditions, the fate and transformation of 2,6-DNT after uptake ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2007.02.003
更新日期:2007-06-01 00:00:00
abstract::In this study, a facile and effective route to prepare hybrid photocatalysts (paper-TiO2, paper-TiO2-AgBr and paper-AgBr-TiO2) has been reported. The preparation procedure consisted of the direct adsorption of the previously synthesized titania nanoparticles (TiO2 sol) to generate the TiO2 nanosphere and the immersion...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128703
更新日期:2020-10-22 00:00:00
abstract::We report results of a multigenerational experiment with Chironomus riparius. Two strains with a high and a low level of genetic variability were exposed to a low, environmentally relevant TBT concentration of 80 μg Sn kg(-1)sedimentdw nominally (time weighted mean, based on measured concentrations: 4.5 μg Sn kg(-1)se...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.03.036
更新日期:2012-08-01 00:00:00
abstract::Paper recycling is an environmental important activity that is carried out in all the countries, but during the recycling process a paper waste is produced. Generally these wastes are placed in landfill sites but it is possible to profit it as secondary fuel and raw material in manufacture furnaces. In this work the c...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.01.049
更新日期:2008-05-01 00:00:00
abstract::Within the rotational scheme developed by the Programme to fight the resistance of Simulium damnosum to chemical larvicides, there was an operational gap at discharges between 5 and 70 m3 s(-1) for the treatment of rivers where resistance to organophosphates was present. The use of permethrin and carbosulfan was precl...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00172-7
更新日期:2001-03-01 00:00:00
abstract::The formation of dichloroacetonitrile (DCAN), dichloroacetamide (DCAcAm) and trichloroacetamide (TCAcAm) during chlorination of secondary effluents was evaluated under different conditions. The formation of DCAN and DCAcAm increased, then decreased with increasing contact time and chlorine dose, while TCAcAm formation...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.08.082
更新日期:2016-02-01 00:00:00
abstract::Dioxins (PCDD + PCDF) and polychlorinated biphenyl (PCB) are potentially hazardous compounds and have structural similarity to thyroid hormones. Our research group on "Dioxins and PCB in Human Milk" was organized in 1997 and has been active for the past three years. We collected breast milk from 80 mothers living in T...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(01)00050-9
更新日期:2001-12-01 00:00:00
abstract::The deterioration of water quality, especially organic pollution in Tai Lake and the Qiantang River, have recently received attention in China. The objectives of this study were to evaluate the formation of halonitromethanes (HNMs) using multiple regression models for chlorination and chloramination and to identify th...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.06.084
更新日期:2015-01-01 00:00:00
abstract::The levels and bioaccumulation of organochlorine pesticides (OCPs) and heavy metals were studied in muscle and liver of three fish species, with two trophic levels, from Lake Awassa, Ethiopia. DDTs were the predominant organic pollutant in all species with a maximum level of 73.28 ng g(-1) wet weight (ww). p,p'-DDE wa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.01.047
更新日期:2013-05-01 00:00:00
abstract::We calculated the sensitivity of Galician forest soils to eutrophication caused by atmospheric deposition of nitrogen compounds, using the Simple Mass Balance (SMB) method as described by [Posch, M., de Vries, W., Hettelingh, J.-P., 1995. Critical loads of sulphur and nitrogen. In: Posch, M., de Smet, P.A.M., Hettelin...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.08.072
更新日期:2006-06-01 00:00:00
abstract::In recent years the behavior and properties of nanoparticles released to the environment have been studied extensively to better assess the potential consequences of their broad use in commercial products. The fate, transport and mobility of nanoparticles in soil were shown to be strongly dependent on environmental co...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.09.018
更新日期:2013-01-01 00:00:00
abstract::The exponential increase in the usage of engineered nanoparticles (ENPs) has raised global concerns due to their potential toxicity and environmental impacts. Nano-TiO2 and nano-ZnO have been extensively used in various applications. Thus, there is a need for determining the toxic potentials of ENPs as well as, to dev...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.08.080
更新日期:2017-11-01 00:00:00
abstract::This study aimed to classify the possible molecular formulas of precursors for disinfection by-products (DBPs) in raw, coagulated, and chlorinated water samples from the U-Tapao Canal, Songkhla, Thailand. The molecular formulas of DBPs in chlorinated water were investigated. Polyaluminum chloride (PACl) was employed a...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128437
更新日期:2021-02-01 00:00:00
abstract::The oxidation of organic micro-pollutants by biogenic manganese oxide nanoparticles (BioMnOx) has been studied with respect to possible implementation of BioMnOx in wastewater treatment. For this it would be prerequisite that microbial Mn(2+) oxidation and BioMnOx-driven pollutant removal can occur in situ, i.e. in th...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.11.059
更新日期:2015-10-01 00:00:00
abstract::In many temperate regions, fuel and oil spills are sometimes managed simply by allowing natural degradation to occur, while monitoring soils and groundwater to ensure that there is no off-site migration or on-site impact. To critically assess whether this approach is suitable for coastal Antarctic sites, we investigat...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.07.040
更新日期:2006-03-01 00:00:00
abstract::A system of recirculating channels was used in this study to examine the long-term effects (29d) of environmentally realistic concentrations of the herbicide diuron (from 0.07 to 7 microg L(-1)) on biofilm communities. The autotrophic activity of biofilms was affected by this herbicide, as reflected by a marked decrea...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.06.017
更新日期:2009-09-01 00:00:00
abstract::Numerous indices have been developed to assess environmental risk of heavy metals in surface sediments, including the total content based geoaccumulation index (I(geo)), exchangeable fraction based risk assessment code (RAC), and biological toxicity test based sediment quality guidelines (SQGs). In this study, the thr...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.07.039
更新日期:2011-10-01 00:00:00
abstract::The photocatalytic oxidation of the organic pollutants with the TiO2 as photocatalyst has been widely studied in the world, and many achievements have been got. The degradation of pollutants is highly related with the photocatalytic activity of TiO2. It is demonstrated that doping ions or oxides to TiO2 is one way to ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2004.01.035
更新日期:2004-06-01 00:00:00
abstract::Metal oxide nanomaterials have exhibited toxicity to a variety of aquatic organisms, especially microbes and invertebrates. To date, few studies have evaluated the toxicity of metal oxide nanomaterials on aquatic vertebrates. Therefore, this study examined effects of ZnO, TiO(2), Fe(2)O(3), and CuO nanomaterials (20-1...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.01.061
更新日期:2011-05-01 00:00:00
abstract::Widespread use of phenols has led to ubiquitous exposure to phenols. In experimental animals, phenols increased resorptions, reduced live litter size and fetal body weights. However, there are limited epidemiological evidences of the relationships between exposure to phenols and pregnancy outcomes. We evaluated the as...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.04.067
更新日期:2013-09-01 00:00:00
abstract::Primary sludge (PS), waste activated sludge (WAS) and a mixture of WAS and PS were fermented at 21 degrees C. The sludge was collected from two plants: the biological nutrient removal (BNR) West End Water Pollution Control Center (WEWPCC) and carbon-removal only South End WPCC (SEWPCC). The PS fermentation predictably...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2010.04.026
更新日期:2010-06-01 00:00:00
abstract::Achieving better understanding phosphorus (P) flows through urban ecosystems is needed to conserve P, as non-renewable phosphate rock deposits become depleted and the global human population increases. A baseline mass flow analysis (MFA) for P developed for the Twin Cities Watershed (TCW, which includes most of the Mi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.03.026
更新日期:2011-08-01 00:00:00
abstract::The adsorption and desorption behaviour of two phenoxyalkanoic acid herbicides (MCPA and mecoprop-p) in a Haplic Cambisol with tillage and grassland management was examined using a batch equilibrium method. Additionally, the effect on adsorption of the simultaneous presence of the two herbicides was also studied. The ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.08.023
更新日期:2013-01-01 00:00:00
abstract::Among reptiles, freshwater turtle species have high potential for metal accumulation because of their long lifespan or their aquatic and terrestrial habits. In order to monitor metal bioaccumulation, determine potential toxic effects, and investigate tools for non-invasive metal sampling in reptiles, we studied lead (...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.05.082
更新日期:2019-09-01 00:00:00