Abstract:
:Amino-decorated Zr-based magnetic Metal-Organic Frameworks composites (Zr-MFCs) were prepared by a facile and efficient strategy. The nano-sized Fe3O4@SiO2 core (about 15 nm) was coated with a shell of Zr-MOFs (about 5 nm) by means of in-situ growth. And, Fe3O4@SiO2@UiO-66 and its amino derivatives (Fe3O4@SiO2@UiO-66-NH2 and Fe3O4@SiO2@UiO-66-Urea) were successfully prepared by using different precursors. The obtained Zr-MFCs were demonstrated to be efficient adsorbents for metal ions/organic dyes removal from aqueous solution, with high adsorption capacity and fast adsorption kinetics. It was found that the amine-decorated MFCs were highly efficient for metal ions/dyes removal compared to raw MFC-O. Among them, MFC-N exhibited the highest capacity for Pb2+ (102 mg g-1) and methylene blue (128 mg g-1), while MFC-O exhibited the highest capacity for methyl orange (219 mg g-1). Moreover, anionic and cationic dyes could be selectively separated and removed from the mixed solution just by adjusting the solution pH with Zr-MFCs as the adsorbents. And these Zr-MFCs materials can be easily regenerated by desorbing metal ions/organic dyes from the sorbents with appropriate eluents, and the adsorption capacity can be remained unchanged after 6 recycles. The obtained results demonstrated the great application potential of the prepared MFCs as fascinating adsorbents for water treatment.
journal_name
Chemospherejournal_title
Chemosphereauthors
Huang L,He M,Chen B,Hu Bdoi
10.1016/j.chemosphere.2018.02.019subject
Has Abstractpub_date
2018-05-01 00:00:00pages
435-444eissn
0045-6535issn
1879-1298pii
S0045-6535(18)30219-4journal_volume
199pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::Foliar emission of volatile organic compounds (VOC) from common Indian plant species was measured. Dynamic flow enclosure technique was used and the gas samples were collected onto Tenax-GC/Carboseive cartridges. The Tenax-GC/Carboseive cartridges were attached to the thermal disorber sample injection system and the g...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.01.046
更新日期:2005-06-01 00:00:00
abstract::Sewage sludge-amended soils may alter their ability to adsorb heavy metals over time, due to the decomposition of sludge-borne organic matter. Thus, we studied Cd, Ni, and Zn adsorption by a sewage sludge-amended soil (Typic Xerofluvent) before and after one-year incubation in both monometal and competitive systems. I...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.12.062
更新日期:2007-06-01 00:00:00
abstract::We investigated the concentrations of 23 elements in groundwater from arsenic (As) contaminated areas of Bangladesh and West Bengal, India to determine the potential human exposure to metals and metalloids. Elevated concentrations of As was found in all five study areas that exceeded the World Health Organization (WHO...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.05.051
更新日期:2015-11-01 00:00:00
abstract::Trivalent organoarsenicals such as methylarsenite (MAs(III)) are considerably more toxic than inorganic arsenate (As(V)) or arsenite (As(III)). In microbial communities MAs(III) exhibits significant antimicrobial activity. Although MAs(III) and other organoarsenicals contribute to the global arsenic biogeocycle, how t...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126911
更新日期:2020-09-01 00:00:00
abstract::The study aimed to evaluate the physiological mechanisms underlying differences in metals and metalloid uptake and tolerance of two tree species cultivated in mining waste material. Two-year old Acer platanoides L. and Tilia cordata Mill. were cultivated in mining sludge characterized by high pH, salinity and an extre...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.05.051
更新日期:2019-08-01 00:00:00
abstract::Spray drift and edge-of-field runoff are regarded as important routes of nonpoint-source pesticide input into aquatic surface waters, with current regulatory risk assessment in Europe focussing largely on spray drift. However, the two routes of entry had rarely been compared directly in the same catchment. To this end...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00601-9
更新日期:2001-11-01 00:00:00
abstract::Surface water can be contaminated with pollutants from multiple sources and contain a vast number of various chemicals. In vitro bioassays are valuable tools to assess the total bioactivity of micropollutants in water samples. Besides anthropogenic chemicals, natural organic matter (NOM) is ubiquitous in water, which ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.02.081
更新日期:2018-06-01 00:00:00
abstract::The behavioral and biochemical responses of Japanese medaka (Oryzias latipes) to acute and subacute (sublethal) levels of chlorpyrifos were studied. In the acute exposure test, medaka were exposed to 0.018, 0.055, 0.166, or 0.500 mg L(-1) chlorpyrifos for 4 d. As a result, fish showed hypoactivity compared to the cont...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.02.042
更新日期:2013-06-01 00:00:00
abstract::This study analyzes the 137Cs behavior in the ponds of Okuma Town from 2015 to 2019 in the Fukushima Dai-ichi nuclear power plant (FDNPP) exclusion zone. A decline in both particulate and dissolved 137Cs activity concentrations was revealed. The decline rate constants for the particulate 137Cs activity concentration w...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.129058
更新日期:2021-02-01 00:00:00
abstract::The design of sustainable, effective and recyclable hybrid catalysts for advanced oxidation processes is highly significant for remediation of the water environment. In this study, we synthesized magnetic Fe3O4-N-doped carbon sphere composite catalysts (Fe3O4-NCS-x) for efficient removal of tetracycline by activating ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128011
更新日期:2021-01-01 00:00:00
abstract::In this study, activated petroleum coke (APC) and commercial activated carbon (CAC) were used in a continuous adsorption column for removal of model naphthenic acids and organics from real oil sands process-affected water (OSPW). Diphenylacetic acid and 2-naphthoic acid, two model naphthenic acid (NA) compounds, were ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.09.078
更新日期:2019-01-01 00:00:00
abstract::Accurate prediction of the sorption of perfluoroalkyl substances (PFASs) in soils is essential for environmental risk assessment. We investigated the effect of solution pH and calculated soil organic matter (SOM) net charge on the sorption of 14 PFASs onto an organic soil as a function of pH and added concentrations o...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.05.012
更新日期:2018-09-01 00:00:00
abstract::Mercury (Hg) is a well-known neurotoxicant but its toxicity depends on the species present. A steady emergence of inorganic Hg in the brain following chronic and accidental exposure to methylmercury (MeHg) has suggested that MeHg can undergo demethylation. The objective of this study is to develop an in vitro model to...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.09.019
更新日期:2008-12-01 00:00:00
abstract::In this paper, the response mechanism of activated sludge exposed to low-dose ozone at less than 20mgO(3)g(-1) total suspended solids (TSS) was studied by analyzing the changes in sludge activity and the evolution of C, N, P and metals from sludge following ozonation. The intracellular ATP concentration was not affect...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.07.047
更新日期:2009-09-01 00:00:00
abstract::This paper evaluates the speciation and partitioning of mercury in two Spanish pulverised coal combustion power plants (PP1 and PP2), equipped with wet limestone-based flue gas desulphurisation facilities (FGD) operating with forced oxidation and re-circulation of FGD water streams. These plants are fed with coal (PP1...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.06.081
更新日期:2011-10-01 00:00:00
abstract::A wild strain of Chaetoceros calcitrans and wild and diuron-resistant strains of Tetraselmis suecica, were exposed to the PSII inhibitor herbicides diuron and irgarol, individually and in mixtures. The effects of three concentrations of diuron and irgarol and four binary mixtures were evaluated on doubling time, relat...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.073
更新日期:2016-05-01 00:00:00
abstract::The effect of dissolved humic acid (HA) on two types of hydrolysis reactions was investigated: (I) dehydrochlorination of gamma-hexachlorocyclohexane (HCH) and 1,1,2,2-tetrachloroethane (TeCA) as a reaction involving hydroxide ions (OH(-)) and (II) hydrolysis of 1-octyl acetate (OA) which is catalyzed by H(+) at the a...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2007.12.001
更新日期:2008-04-01 00:00:00
abstract::Use of wastewater is known to provide nutrients for crop plants, but its potential to improve phosphorus (P) availability in semi-arid regions is poorly understood. In this study, seasonal changes in soil P availability as well as associated phyiscochemical and biochemical indicators were investigated from the wastewa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.124725
更新日期:2020-01-01 00:00:00
abstract::The number, morphology and elemental composition of nanoparticles (<100 nm) in marine water was investigated using Variable Pressure Scanning Electron Microscopy (VP-SEM) and Energy-dispersive X-ray spectroscopy (EDS). Preliminary research conducted in the Baltic Sea showed that the number of nanoparticles in seawater...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.05.022
更新日期:2018-09-01 00:00:00
abstract::Sulfonamides (SAs) are a group of antibiotic drugs widely used in veterinary medicine. The contamination of the environment by these pharmaceuticals has raised concern in recent years. However, knowledge of their (eco)toxicity is still very basic and is restricted to just a few of these substances. Even though their t...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.06.058
更新日期:2011-10-01 00:00:00
abstract::Dioxins (PCDD + PCDF) and polychlorinated biphenyl (PCB) are potentially hazardous compounds and have structural similarity to thyroid hormones. Our research group on "Dioxins and PCB in Human Milk" was organized in 1997 and has been active for the past three years. We collected breast milk from 80 mothers living in T...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(01)00050-9
更新日期:2001-12-01 00:00:00
abstract::This study investigated the quantity and quality of dissolved organic matter (DOM) released from wetland-plant derived biochar under various extracting conditions (deionized water, 0.1 mol/L HCl, 0.1 mol/L NaOH, and 0.1 mol/L NaCl) by using fluorescence excitation-emission matrix (EEM) spectrophotometry with parallel ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.08.110
更新日期:2018-12-01 00:00:00
abstract::Partitioning of dioxins, dibenzofurans and the dioxin-like coplanar PCBs was determined by congener-specific high resolution gc-ms analysis of compounds in 6 tissue samples each from 5 women. Samples were whole blood obtained prior to delivery; maternal adipose tissue, cord blood and placenta obtained during cesarean ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(98)00247-1
更新日期:1998-10-01 00:00:00
abstract::In this study, an analytical method was optimized for the determination of bisphenol-A (BPA), triclosan (TCS) and 4-n-nonylphenol (4n-NP), environmental contaminants with potential endocrine disruptive activities, in human tissues. The method consisted of a liquid extraction step, derivatization with pentafluorobenzoy...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.01.002
更新日期:2012-05-01 00:00:00
abstract::This paper reports on the use of platinum electrode modified with kaolin (K/Pt) and square wave voltammetry for analytical detection of trace lead(II) in pure water, orange and apple samples. The electroanalytical procedure for determination of the Pb(II) comprises two steps: the chemical accumulation of the analyte u...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.04.017
更新日期:2009-08-01 00:00:00
abstract::Persulfate based advanced oxidation process is a promising technology for refractory contaminants removal. Cobalt is considered as the most efficient metal in catalyzing peroxymonosulfate decomposition. Although different cobalt based nanomaterials have been developed, easy aggregation and metal ion leaching during ca...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.125577
更新日期:2020-04-01 00:00:00
abstract::The mosquito Aedes aegypti is the main vector of Dengue, Chikungunya, Zika, and yellow fever viruses, which are responsible for high human morbidity and mortality. The fight against these pathogens is mainly based on the control of the insect vector with the use of insecticides. Among insecticides, spinosad bioinsecti...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.01.068
更新日期:2019-04-01 00:00:00
abstract::There is a lack of consensus on the charge state of active gold species in catalytic CO oxidation reaction. Herein, Au/SBA-15 catalyst was prepared by room temperature ozone treatment. Through diffuse reflectance Fourier-transform infrared spectroscopy (DRIFTS), two different gold species, Au0 and Auδ- with CO adsorpt...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126274
更新日期:2020-07-01 00:00:00
abstract::A fluorescence enhancement-based immunoassay has been developed for the detection of the polycyclic aromatic hydrocarbons (PAH), benzo[a]pyrene (BaP), in aqueous solutions. The results of this study show that BaP, which inefficiently fluoresces in aqueous solution, displays enhanced fluorescence when bound to the anti...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.01.008
更新日期:2016-05-01 00:00:00
abstract::Soil and atmospheric concentrations, dry deposition and soil-air gas exchange of organochlorine pesticides (OCPs) were investigated at an industrial site in Aliaga, Izmir, Turkey. Current-use pesticides, endosulfan and chlorpyrifos, had the highest atmospheric levels in summer and winter. Summertime total (gas+particl...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.09.032
更新日期:2009-11-01 00:00:00