Evaluating fluorescent dissolved organic matter released from wetland-plant derived biochar: Effects of extracting solutions.

Abstract:

:This study investigated the quantity and quality of dissolved organic matter (DOM) released from wetland-plant derived biochar under various extracting conditions (deionized water, 0.1 mol/L HCl, 0.1 mol/L NaOH, and 0.1 mol/L NaCl) by using fluorescence excitation-emission matrix (EEM) spectrophotometry with parallel factor analysis (PARAFAC). Concentrations of dissolved organic carbon (DOC) released from biochar extracted in different extracting solutions ranged from 0.69 g/L to 1.22 g/L with the total contents of 13.7-23.5 g DOC/kg. The average DOC content was highest in the alkaline solution and lowest in the deionized water. Three humic acid-like substances, one fulvic acid-like substance and one tyrosine-like substance were identified. The distributions of the identified components in DOM were distinctively different among various extracts, and humic acid-like components were the dominant materials. The extraction conditions could affect significantly humic acid-like and fulvic acid-like fluorescence. The results would be beneficial to understand the biochar's effects and processes in possible environmental applications.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Wu H,Dong X,Liu H

doi

10.1016/j.chemosphere.2018.08.110

subject

Has Abstract

pub_date

2018-12-01 00:00:00

pages

638-644

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(18)31585-6

journal_volume

212

pub_type

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