Assessing the chromium mobility in ashes through SiO2-Al2O3-Fe2O3-CaO system: The role of composition.

Abstract:

:Given the millions of coal-fired power stations worldwide and the generalization of co-firing technologies in the near future, the aqueous extraction experiments were taken to study the effects of oxides on Cr mobility in ashes through SiO2-Al2O3-Fe2O3-CaO system. The results identify that both the component and the species of Cr in samples are vital factors to govern the fate of Cr during combustion. Although Cr-oxide hardly reacts with Al2O3, SiO2, and mixtures at 900 °C, the immobilization of Cr in Si-Al glass is ascribable to the heat-driven phase transformation of Cr-rich clay. The strong capture of Cr-oxide by CaO leads to the primary extraction of active Cr with the high toxicity and mobility; however, the opposite effect is found by Fe2O3. But the interactions of Al-/Si- oxides with others can trigger some changes in Cr mobility, wherein there is the lowest mobility of Cr in the case of Cr entering into the structures of Fe-rich SiO2/Si-Al glass during combustion. Thus, without regard to the sample source, it is effective to reduce the environmental risk of Cr in ashes through raising SiO2 and reducing MCaO/MFe2O3 < 5/4 prior to combustion.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Yang Z,Wang C,Li Y,Yang S,Zhang W,Li Y

doi

10.1016/j.chemosphere.2020.127112

subject

Has Abstract

pub_date

2020-10-01 00:00:00

pages

127112

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(20)31305-9

journal_volume

257

pub_type

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