Trichloroethylene adsorption by pine needle biochars produced at various pyrolysis temperatures.

Abstract:

:In this study, pine needles were converted to biochar (BC) at different pyrolysis temperatures of 300, 500, and 700 °C to sorb trichloroethylene (TCE), and the changes in BC properties with each temperature were evaluated. Pyrolysis temperature showed a pronounced effect on BC properties. Decreases in molar H/C and O/C ratios resulted from removing O- and H-containing functional groups with increasing temperature, and produced high aromaticity and low polarity BCs. BCs produced at higher temperature showed greater TCE removal efficiency from water due to their high surface area, micro-porosity, and carbonized extent. The performance of various BCs for TCE removal was assessed by the Freundlich, Langmuir, Temkin, and Dubinin-Radushkevich adsorption models, among which the Temkin and Dubinin-Radushkevich models best described TCE adsorption onto various BCs, indicating prevailing sorption mechanism as pore-filling.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Ahmad M,Lee SS,Rajapaksha AU,Vithanage M,Zhang M,Cho JS,Lee SE,Ok YS

doi

10.1016/j.biortech.2013.06.033

subject

Has Abstract

pub_date

2013-09-01 00:00:00

pages

615-22

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(13)00952-8

journal_volume

143

pub_type

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