Mercury adsorption of modified mulberry twig chars in a simulated flue gas.

Abstract:

:Mulberry twig chars were prepared by pyrolysis, steam activation and impregnation with H2O2, ZnCl2 and NaCl. Textural characteristics and surface functional groups were performed using nitrogen adsorption and FTIR, respectively. Mercury adsorption of different modified MT chars was investigated in a quartz fixed-bed absorber. The results indicated that steam activation and H2O2-impregnation can improve pore structure significantly and H2O2-impregnation and chloride-impregnation promote surface functional groups. However, chloride-impregnation has adverse effect on pore structure. Mercury adsorption capacities of impregnated MT chars with 10% or 30% H2O2 are 2.02 and 1.77 times of steam activated MT char, respectively. Mercury adsorption capacity of ZnCl2-impregnated MT char increase with increasing ZnCl2 content and is better than that of NaCl-impregnated MT char at the same chloride content. The modified MT char (MT873-A-Z5) prepared by steam activation following impregnation with 5% ZnCl2 exhibits a higher mercury adsorption capacity (29.55 μg g(-1)) than any other MT chars.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Shu T,Lu P,He N

doi

10.1016/j.biortech.2013.02.087

subject

Has Abstract

pub_date

2013-05-01 00:00:00

pages

182-7

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(13)00322-2

journal_volume

136

pub_type

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