Abstract:
:Formic acid is the main breakdown product of mild hydrothermal treatment of carbohydrates. Further conversion to methanol was achieved using Cu as catalyst and Zn as reductant under hydrothermal conditions of 250-325 °C for 3-12 h. Both Cu and Zn used were commercial Cu and Zn powders with particle sizes of 200 mesh. A methanol yield of 32% was achieved at 300 °C for 5h with 6.5 mmol of Cu, 12 mmol of Zn and a filling rate of 44%. Thus, this process may provide a promising solution to producing methanol from biomass by converting carbohydrates into formic acid.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Liu J,Zeng X,Cheng M,Yun J,Li Q,Jing Z,Jin Fdoi
10.1016/j.biortech.2012.03.032subject
Has Abstractpub_date
2012-06-01 00:00:00pages
658-62eissn
0960-8524issn
1873-2976pii
S0960-8524(12)00475-0journal_volume
114pub_type
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