Abstract:
:Furfural is a biomass derived-chemical that can be used to replace petrochemicals. In this study, the acid-catalyzed conversion of xylose and xylan to furfural by microwave-assisted reaction was investigated at selected ranges of temperature (140-190°C), time (1-30 min), substrate concentration (1:5-1:200 solid:liquid ratio), and pH (2-0.13). We found that a temperature of 180°C, a solid:liquid ratio of 1:200, a residence time of 20 min, and a pH of 1.12 gave the best furfural yields. The effect of different Brønsted acids on the conversion efficiency of xylose and xylan was also evaluated, with hydrochloric acid being found to be the most effective catalyst. The microwave-assisted process provides highly efficient conversion: furfural yields obtained from wheat straw, triticale straw, and flax shives were 48.4%, 45.7%, and 72.1%, respectively.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Yemiş O,Mazza Gdoi
10.1016/j.biortech.2011.04.050subject
Has Abstractpub_date
2011-08-01 00:00:00pages
7371-8issue
15eissn
0960-8524issn
1873-2976pii
S0960-8524(11)00564-5journal_volume
102pub_type
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