Abstract:
:A study of the vibrational behavior of five saturated monoacid triacylglycerides is performed by Raman spectroscopy at room temperature in the 3100-500 cm(-1) spectral range. The splitting of the CO stretching mode leads to conclude on the existence of two or three geometries of CO in the "knot" group OCO. The CO stretching mode seems to be a good tool for distinguishing the polymorphic forms of the studied triglycerides. The assignments of the different CH stretching modes are performed in the 1500-500 cm(-1) spectral range. The I(2845)/I(2880) (in the CH stretching spectral region) and I(1445)/I(1296) intensity ratios (between the maximal intensity I(1445) of the CH(2) scissoring mode and the maximal intensity I(1296) of the skeletal vibration of (CH(2))(n) in-phase twist) seem to depend on the type of polymorphic forms of these molecules.
journal_name
Chem Phys Lipidsjournal_title
Chemistry and physics of lipidsauthors
Bresson S,El Marssi M,Khelifa Bdoi
10.1016/j.chemphyslip.2004.12.009subject
Has Abstractpub_date
2005-04-01 00:00:00pages
119-29issue
2eissn
0009-3084issn
1873-2941pii
S0009-3084(05)00010-1journal_volume
134pub_type
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