Bulk and compound-specific stable isotope ratio analysis for authenticity testing of organically grown tomatoes.

Abstract:

:Until now, there has been a lack of analytical methods that can reliably verify the authenticity of organically grown plants and derived organic food products. In this study, stable isotope ratio analysis of hydrogen (H, δ2H), carbon (C, δ13C), nitrogen (N, δ15N), oxygen (O, δ18O) and sulfur (S, δ34S) was conducted along the tomato passata production process using organic and conventionally grown tomatoes from two Italian regions over two years. A gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS) based method was developed and applied for analysis of C and N isotope ratios in amino acids derived from tomatoes. Of the bulk isotope ratios, δ15N was the most significant parameter for discriminating organic from conventional products. The classification power was improved significantly by compound-specific isotope analysis regardless of the production years and regions. We conclude that isotope analysis of amino acids is a novel analytical tool for complementing existing certification and control procedures in the organic tomato sector.

journal_name

Food Chem

journal_title

Food chemistry

authors

Bontempo L,van Leeuwen KA,Paolini M,Holst Laursen K,Micheloni C,Prenzler PD,Ryan D,Camin F

doi

10.1016/j.foodchem.2020.126426

subject

Has Abstract

pub_date

2020-07-15 00:00:00

pages

126426

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(20)30287-9

journal_volume

318

pub_type

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