Abstract:
:Four model polyurethane (PU) hard segments were synthesized by reaction of butanol with four typical diisocyanates. The four diisocyanates were aromatic 4,4'-diphenylmethane diisocyanate (4,4'-MDI) and MDI-50 (50% mixture of 2,4'-MDI and 4,4'-MDI), cycloaliphatic 4,4'-dicyclohexylmethane diisocyanate (HMDI) and linear aliphatic 1,6-hexamethylene diisocyanate (HDI). FTIR, 1H NMR, 13C NMR, MS, X-ray and DSC methods were employed to determine their structures and to analyse their crystallization behaviours and hydrogen bonding interactions. Each of the four PU compounds prepared in the present work displays unique spectral characteristics. The FTIR bands and NMR resonance peaks assigned in the four samples thus provide a reliable database and starting point for investigating the relationship between hard segment structure and the crystallization and hydrogen bonding behaviour in more complex-segmented PU compositions.
journal_name
R Soc Open Scijournal_title
Royal Society open scienceauthors
Jiang L,Ren Z,Zhao W,Liu W,Liu H,Zhu Cdoi
10.1098/rsos.180536subject
Has Abstractpub_date
2018-07-25 00:00:00pages
180536issue
7issn
2054-5703pii
rsos180536journal_volume
5pub_type
杂志文章abstract::Biochar, as a soil amendment in agriculture, has attracted considerable attention. In the study, the fate and toxicity of the herbicide fenoxaprop-ethyl were evaluated in soils with and without 5% rice husk biochar amendment. Fenoxaprop-ethyl and metabolite fenoxaprop degradation followed first-order kinetics in the t...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.171875
更新日期:2018-05-02 00:00:00
abstract::We simulate an actin filament as an automaton network. Every atom takes two or three states and updates its state, in discrete time, depending on a ratio of its neighbours in some selected state. All atoms/automata simultaneously update their states by the same rule. Two state transition rules are considered. In semi-...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.181198
更新日期:2019-01-23 00:00:00
abstract::Selection among alternative theoretical models given an observed dataset is an important challenge in many areas of physics and astronomy. Reversible-jump Markov chain Monte Carlo (RJMCMC) is an extremely powerful technique for performing Bayesian model selection, but it suffers from a fundamental difficulty and it re...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.150030
更新日期:2015-06-24 00:00:00
abstract::Current demographic trends in the UK include a fast-growing elderly population and dropping birth rates, and demand for social care among the aged is rising. The UK depends on informal social care-family members or friends providing care-for some 50% of care provision. However, lower birth rates and a greying populati...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.190029
更新日期:2019-07-17 00:00:00
abstract::In this contribution, olefin block copolymers were produced via chain shuttling polymerization (CSP), using a new combination of catalysts and a chain shuttling agent (CSA) diethylzinc (ZnEt2). The binary catalyst system included nonbridged half-titanocene catalyst, Cp*TiCl2(O-2,6-iPr2C6H3) (Cat A) and bis(phenoxy-imi...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.182007
更新日期:2019-04-10 00:00:00
abstract::Recognition plays an important role in the formation and organization of animal groups. Many animals are capable of class-level recognition, discriminating, for example, on the basis of species, kinship or familiarity. Individual recognition requires that animals recognize distinct cues, and learn to associate these w...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.191703
更新日期:2020-07-08 00:00:00
abstract::Adult body size in holometabolus insects is directly proportional to the time spent during the larval period. The larval duration can be divided into two parts: (i) pre-critical duration-time required to attain a critical size/critical weight that would result in successful completion of development and metamorphosis ...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.191910
更新日期:2020-06-10 00:00:00
abstract::The formation mechanism of pentazolate anion (PZA) is not yet clear. In order to present the possible formation pathways of PZA, the potential energy surfaces of phenylpentazole (PPZ), phenylpentazole radical (PPZ-R), phenylpentazole radical anion (PPZ-RA), PPZ and m-chloroperbenzoic acid (m-CPBA), p-pentazolylphenola...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.172269
更新日期:2018-05-23 00:00:00
abstract::The constraint release (CR) mechanism has important effects on polymer relaxation and the chains will show different relaxation behaviour in conditions of monodisperse, bidisperse and other topological environments. By comparing relaxation data of linear polyisoprene (PI) chains dissolved in very long matrix and monod...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.191046
更新日期:2020-03-18 00:00:00
abstract::Anastasis is a natural cell recovery phenomenon that rescues cells from the brink of death. Programmed cell death such as apoptosis has been traditionally assumed to be an intrinsically irreversible cascade that commits cells to a rapid and massive demolition. Interestingly, recent studies have demonstrated recovery o...
journal_title:Royal Society open science
pub_type: 杂志文章,评审
doi:10.1098/rsos.180442
更新日期:2018-09-19 00:00:00
abstract::Comprehensive diagnosis of polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F) emissions was systematically conducted on three hazardous waste incinerators (HWIs). Results indicated that PCDD/F mainly existed in the solid phase before the bag filter. This was especially true for higher chlorinated dioxin and fu...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.172056
更新日期:2018-07-11 00:00:00
abstract::Heteroepitaxial growth of aluminum nitride (AIN) has been explored by experiments, but the corresponding growth mechanism is still unrevealed. Here, we use molecular dynamics simulations to study effects of temperature and N : Al flux ratio on deposited AlN. When the temperature increases from 1000 K to 2000 K with an...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.180629
更新日期:2018-08-15 00:00:00
abstract::[This corrects the article DOI: 10.1098/rsos.150635.]. ...
journal_title:Royal Society open science
pub_type: 已发布勘误
doi:10.1098/rsos.201430
更新日期:2020-11-11 00:00:00
abstract::Patient-specific modelling of haemodynamics in arterial networks has so far relied on parameter estimation for inexpensive or small-scale models. We describe here a Bayesian uncertainty quantification framework which makes two major advances: an efficient parallel implementation, allowing parameter estimation for more...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.182229
更新日期:2019-10-16 00:00:00
abstract::Pseudohyphal growth of the dimorphic yeast Saccharomyces cerevisiae is analysed using two-dimensional top-down binary images. The colony morphology is characterized using clustered shape primitives (CSPs), which are learned automatically from the data and thus do not require a list of predefined features or a priori k...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.180820
更新日期:2018-10-17 00:00:00
abstract::Many scientists communicate with the public about risks associated with scientific issues, but such communication may have unintended consequences for how the public views the political orientations and the credibility of the communicating scientist. We explore this possibility using an experiment with a nationally re...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.170505
更新日期:2018-02-21 00:00:00
abstract::The evolution of multicellularity was a major transition in evolution and set the stage for unprecedented increases in complexity, especially in land plants and animals. Here, we explore the genetics underlying a de novo origin of multicellularity in a microbial evolution experiment carried out on the green alga Chlam...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.180912
更新日期:2018-08-29 00:00:00
abstract::In this paper, recent progress in graphic statics is combined with Williot displacement diagrams to create a graphical description of both statics and kinematics for two- and three-dimensional pin-jointed trusses. We begin with reciprocal form and force diagrams. The force diagram is dissected into its component cells...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.170202
更新日期:2017-05-24 00:00:00
abstract::Varanopids are a basal clade of small- to medium-sized non-therapsid synapsids, whose range extends from the late Pennsylvanian to the late middle Permian, and are found in North America, Russia, Europe and South Africa. The greatest varanopid diversity is observed at the fossiliferous cave deposits near Richards Spur...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.191297
更新日期:2019-10-23 00:00:00
abstract::The emerging carbon quantum dots (CQDs) have been attracting significant attention for their prominent fluorescence, excellent stability and outstanding biocompatibility. Here, we report a facile one-step synthesis of highly fluorescent CQDs by using phthalic acid and triethylenediamine hexahydrate as precursors throu...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.180245
更新日期:2018-07-11 00:00:00
abstract::Polylactic electrospun porous fibres have been widely used in tissue engineering scaffolds. However, the application of linear polylactic is limited due to its poor hydrophilicity, which leads to phase separation and has been seldom used in porous fibre preparation. Instead, branching polylactic acts as a new effectiv...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.180134
更新日期:2018-09-12 00:00:00
abstract::The aim of this study was to obtain an electrochemical device between the electrostatic interaction of the electropolymerized porphyrin {CoTPyP[RuCl3(dppb)]4}, where TPyP = 5,10,15, 20-tetrapyridilphorphyrin and dppb = 1,4-bis(diphenylphosphino)butane, and gold nanoparticles (AuNPsn-), to be used as a voltammetric sen...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.170675
更新日期:2017-12-20 00:00:00
abstract::The evolution of spoken languages has been studied since the mid-nineteenth century using traditional historical comparative methods and, more recently, computational phylogenetic methods. By contrast, evolutionary processes resulting in the diversity of contemporary sign languages (SLs) have received much less attent...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.191100
更新日期:2020-01-22 00:00:00
abstract::The rapid rise of the CO2 level in the atmosphere has spurred the development of CO2 capture methods such as the use of biomimetic complexes that mimic carbonic anhydrase. In this study, model complexes with tris(2-pyridylmethyl)amine (TPA) were synthesized using various transition metals (Zn2+, Cu2+ and Ni2+) to cont...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.190407
更新日期:2019-08-07 00:00:00
abstract::Cetacean energy stores are known to vary according to life history, reproductive status and time of year; however, the opportunity to quantify these relationships is rare. Using a unique set of historical whaling records from Western Australia (1952-1963), we investigated energy stores of large cetaceans with differin...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.160290
更新日期:2017-03-15 00:00:00
abstract::A new Triassic neopterygian is described on the basis of a large three-dimensional neurocranium from the Rhaetian (Late Triassic) of the Kössen Formation (Schesaplana, Grisons, Switzerland). CT scanning reveals neurocranial features similar to Dapedium, suggesting that this new genus, Scopulipiscis saxciput gen. et sp...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.180497
更新日期:2018-08-15 00:00:00
abstract::The adaptive significance of zebra stripes has thus far eluded understanding. Many explanations have been suggested, including social cohesion, thermoregulation, predation evasion and avoidance of biting flies. Identifying the associations between phenotypic and environmental factors is essential for testing these hyp...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.140452
更新日期:2015-01-14 00:00:00
abstract::The study of the evolution of abiotic niches can be informative regarding the speciation drivers in a given group. Yet, two factors that could potentially affect niche evolution have seldom been addressed concomitantly, which are biotic interactions and geographical isolation. In this study, we used as a model group t...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.170293
更新日期:2017-11-01 00:00:00
abstract::Animals living in complex environments experience differing risks of predation depending upon their location within the landscape. An animal could reduce the risk it experiences by remaining in a refuge site, but it may need to emerge from its refuge and enter more dangerous sites for feeding and other activities. Her...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.160910
更新日期:2017-01-11 00:00:00
abstract::Social information use is common in a wide range of group-living animals, notably in humans. The role it plays in decision-making could be a key to understanding how social groups make collective decisions. The observation of road-crossing behaviours in the presence of other individuals is an ideal means to study the ...
journal_title:Royal Society open science
pub_type: 杂志文章
doi:10.1098/rsos.160739
更新日期:2017-02-15 00:00:00