Graft copolymer based on (sodium alginate-g-acrylamide): Characterization and study of Water swelling capacity, metal ion sorption, flocculation and resistance to biodegradability.

Abstract:

:Graft copolymer of alginate and acrylamide was synthesized by grafting acrylamide chains on to alginate by free radical polymerization using potassium bromate/thiourea redox system in an inert atmosphere. The reaction conditions for maximum grafting have been optimized by varying the reaction variables, including the concentration of acrylamide (3.0×10(2)-9.3×10(2)moldm(-3)), potassium bromate (8×10(-3)-16×10(-3)moldm(-3)), thiourea (1.6×10(-3)-4.8×10(-3)moldm(-3)), sulphuric acid (3.0×10(-3)-7×10(-3)moldm(-3)), alginate (0.6-1.6gdm(-3)) along with time duration (60-180min) and temperature (30-50°C). Water swelling capacity, metal ion sorption, flocculation and resistance to biodegradability studies of synthesized graft copolymer have been performed with respect to the parent polymer. The grafted polymers were characterized by FTIR spectroscopy and thermo gravimetric analysis.

journal_name

Int J Biol Macromol

authors

Sand A,Vyas A,Gupta AK

doi

10.1016/j.ijbiomac.2015.11.085

subject

Has Abstract

pub_date

2016-09-01 00:00:00

pages

37-43

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(15)30180-X

journal_volume

90

pub_type

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