Abstract:
:Quercetin found chelate cadmium ions, scavenge free radicals produced by cadmium. Hence new complex, quercetin with cadmium was synthesised, and the synthesised complex structures were determined by UV-vis spectrophotometry, infrared spectroscopy, thermogravimetry and differential thermal analysis techniques (UV-vis, IR, TGA and DTA). The equilibrium stability constants of quercetin-cadmium complex were determined by Job's method. The determined stability constant value of quercetin-cadminum complex at pH 4.4 is 2.27×10(6) and at pH 7.4 is 7.80×10(6). It was found that the quercetin and cadmium ion form 1:1 complex in both pH 4.4 and pH 7.4. The structure of the compounds was elucidated on the basis of obtained results. Furthermore, the antioxidant activity of the free quercetin and quercetin-cadmium complexes were determined by DPPH and ABTS assays.
journal_name
Food Chemjournal_title
Food chemistryauthors
Ravichandran R,Rajendran M,Devapiriam Ddoi
10.1016/j.foodchem.2013.09.080subject
Has Abstractpub_date
2014-03-01 00:00:00pages
472-8eissn
0308-8146issn
1873-7072pii
S0308-8146(13)01345-9journal_volume
146pub_type
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