Abstract:
:Acid scavengers are frequently used as stabilizer compounds in a variety of applications. When used to stabilize volatile compounds such as nerve agents, the lower volatility and higher stability of acid scavengers make them more persistent in a post-event forensic setting. Compound-specific isotope analysis of carbon, nitrogen, and hydrogen in three acid-scavenging compounds (N,N-diethylaniline, tributylamine, and triethylamine) were used as a tool for distinguishing between different samples. Combined analysis of multiple isotopes improved sample resolution, for instance differentiation between triethylamine samples improved from 80% based on carbon alone to 96% when combining with additional isotope data. The compound-specific methods developed here can be applied to instances where these compounds are not pure, such as when mixed with an agent or when found as a residue. Effective sample matching can be crucial for linking compounds at multiple event sites or linking a supply inventory to an event.
journal_name
J Forensic Scijournal_title
Journal of forensic sciencesauthors
Moran JJ,Kreuzer HW,Carman AJ,Wahl JH,Duckworth DCdoi
10.1111/j.1556-4029.2011.01959.xsubject
Has Abstractpub_date
2012-01-01 00:00:00pages
60-3issue
1eissn
0022-1198issn
1556-4029journal_volume
57pub_type
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