Abstract:
:Cocontinuous phase structures of immiscible polymers can be developed under appropriate melt-blending conditions. Because of the presence of interfacial tension, such cocontinuous structures start to coarsen when heated to a temperature higher than the melting/softening temperature of both phases. In this study, a method for controllable growth of gradient porous structures utilizing variable coarsening rates in a gradient temperature field was investigated. The phase structure coarsens at a higher rate in higher temperature regions but at a slower rate in lower temperature regions, resulting in the generation of a gradient phase morphology. Subsequent dissolution of one phase in the binary blend yields a gradient porous structure made of the remaining polymer component. A polystyrene/poly(lactic acid) (PLA) blend was used as a model system. By designing proper thermal boundary conditions and introducing different thermal gradients during annealing, different types of gradient porous structures of PLA were created.
journal_name
Biomacromoleculesjournal_title
Biomacromoleculesauthors
Yao D,Zhang W,Zhou JGdoi
10.1021/bm900008dsubject
Has Abstractpub_date
2009-05-11 00:00:00pages
1282-6issue
5eissn
1525-7797issn
1526-4602journal_volume
10pub_type
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