Abstract:
:Samples of riverine and coastal, filtered (filter pore size 0.2 microm) water were exposed to short-term sunlight irradiation which reduced their absorbance in the UV and visible regions. Absorbance losses in coastal chromophoric dissolved organic matter (CDOM) were up to 10-fold smaller than those in riverine CDOM. Accompanying changes of absorbance spectra shapes (increased slope parameter) were, probably, a result of decrease of the mean molecular size of light absorbing organic matter. The potential of coastal CDOM to photodegradation was smaller and was exhausted during the course of a day-long experiment. A distinctive feature of spectral changes after sunlight exposure was a maximum absorbance decrease which appeared at approximately 300 nm in riverine and at approximately 280 nm in coastal water. That selective absorbance loss has been ascribed in both cases to the disappearance of chromophores of terrestrial origin which, in coastal water, had a lower mean molecular size (due to flocculation and/or prior photodegradation) but, nevertheless, retained their molecular properties.
journal_name
Chemospherejournal_title
Chemosphereauthors
Grzybowski Wdoi
10.1016/s0045-6535(99)00266-0subject
Has Abstractpub_date
2000-06-01 00:00:00pages
1313-8issue
12eissn
0045-6535issn
1879-1298pii
S0045653599002660journal_volume
40pub_type
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