Air-water exchange of polycyclic aromatic hydrocarbons in the New York-New Jersey, USA, Harbor Estuary.

Abstract:

:Polycyclic aromatic hydrocarbons (PAHs, n = 36) were measured in the gas and particle phases in the atmosphere and the dissolved and particle phases in the waters of the New York-New Jersey Harbor Estuary, USA, during a weeklong intensive field campaign in July 1998. Mean total (gas + particulate) phenanthrene and pyrene concentrations were 3.3 and 0.33 ng/m3, respectively, over Raritan Bay, and 14 and 1.1 ng/ml, respectively, over New York Harbor. Similar PAH profiles (p values < 0.01) in the atmospheric gas phase and the dissolved phase in water demonstrate the close coupling of the air and water compartments. Air-water exchange fluxes of PAHs estimated using shore-based air data lead to erroneous flux estimates when compared to those derived using over-water air samples. The gross absorptive air-water flux dominates atmospheric loadings (wet, dry particle, gas absorption) to the estuary for PAHs of molecular weight < 234 g/mol. Dry particle deposition is increasingly more important for the higher-molecular-weight, particle-bound PAH species. Gross volatilization dominates gross absorption for the majority of PAHs in the New York-New Jersey Harbor Estuary.

journal_name

Environ Toxicol Chem

authors

Gigliotti CL,Brunciak PA,Dachs J,Glenn TR 4th,Nelson ED,Totten LA,Eisenreich SJ

subject

Has Abstract

pub_date

2002-02-01 00:00:00

pages

235-44

issue

2

eissn

0730-7268

issn

1552-8618

journal_volume

21

pub_type

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