Enhanced bioaromatics synthesis via catalytic co-pyrolysis of cellulose and spent coffee ground over microporous HZSM-5 and HY.

Abstract:

:Catalytic co-pyrolysis (CCP) of spent coffee ground (SCG) and cellulose over HZSM-5 and HY was characterized thermogravimetrically, and a catalytic pyrolysis of two samples was conducted using a tandem micro reactor that directly connected with gas chromatography-mass spectrometry. To access the more fundamental investigations on CCP, the effects of the zeolite pore structure, reaction temperature, in-situ/ex-situ reaction mode, catalyst to feedstock ratio, and the SCG and cellulose mixing ratio were experimentally evaluated. The temperature showing the highest thermal degradation rate of cellulose with SCG slightly delayed due to the interactions during the thermolysis of two samples. HZSM-5 in reference to HY produced more aromatic hydrocarbons from CCP. With respect to the reaction temperature, the formation of aromatic hydrocarbons increased with the pyrolytic temperature. Moreover, the in-situ/ex-situ reaction mode, catalyst/feedstock, and cellulose/SCG ratio were optimized to improve the aromatic hydrocarbon yield.

journal_name

Environ Res

journal_title

Environmental research

authors

Lee HW,Farooq A,Jang SH,Kwon EE,Jae J,Lam SS,Jung SC,Park YK

doi

10.1016/j.envres.2020.109311

subject

Has Abstract

pub_date

2020-05-01 00:00:00

pages

109311

eissn

0013-9351

issn

1096-0953

pii

S0013-9351(20)30204-8

journal_volume

184

pub_type

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