Abstract:
:N-doped NaTaO(3) compounds (NaTaO(3-)(x)N(x)) with nano-cubic morphology were successfully synthesized by one-step hydrothermal method and Methyl Orange (MO) was used as a model dye to evaluate their photocatalytic efficiency under visible-light irradiation. The as-prepared NaTaO(3-)(x)N(x) samples were characterized by various techniques, such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and UV-vis diffuse reflectance spectra and GC-MS. The results indicate that NaTaO(3-)(x)N(x) displays a pure perovskite structure when the synthesis temperature is higher than 180°C. Moreover, as observed by SEM images, the particles of resultant NaTaO(3-)(x)N(x) show cubic morphology with the edge length of 200-500nm, which can be easily removed by filtration after photocatalytic reaction. Doping of N increases the photocatalytic activity of NaTaO(3), and NaTaO(2.953)N(0.047) shows the highest visible-light photocatalytic activity for the degradation of MO. Based on the experiment results, a possible mechanism of the photocatalysis over NaTaO(3-)(x)N(x) and the photodegradation pathway of MO were proposed.
journal_name
Chemospherejournal_title
Chemosphereauthors
Liu DR,Jiang YS,Gao GMdoi
10.1016/j.chemosphere.2011.01.033subject
Has Abstractpub_date
2011-06-01 00:00:00pages
1546-52issue
11eissn
0045-6535issn
1879-1298pii
S0045-6535(11)00049-Xjournal_volume
83pub_type
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