Vapor pressure of solid polybrominated diphenyl ethers determined via Knudsen effusion method.

Abstract:

:Polybrominated diphenyl ethers (PBDEs) are flame retardants used in a variety of consumer products. The solid vapor pressures of BDE 15 and BDE 209 were determined by using the Knudsen effusion method, and the values measured extrapolated to 298.15 K are 3.12 × 10(-3) and 9.02 × 10(-13) Pa, respectively. The enthalpies of sublimation for these compounds have also been estimated by using the Clausius-Clapeyron equation and are 102.0 ± 3.5 and 157.1 ± 3.5 kJ/mol, respectively. In addition, the melting points and enthalpies of fusion were measured by differential scanning calorimetry.

journal_name

Environ Toxicol Chem

authors

Fu J,Suuberg EM

doi

10.1002/etc.621

subject

Has Abstract

pub_date

2011-10-01 00:00:00

pages

2216-9

issue

10

eissn

0730-7268

issn

1552-8618

journal_volume

30

pub_type

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