Detection of Dechlorane Plus and brominated flame retardants in marketed fish in Japan.

Abstract:

:Fish samples purchased from Japanese markets were analyzed for Dechlorane Plus (DP)(syn-, anti-), polybrominated diphenyl ether (PBDE), and hexabromocyclododecane (HBCD)(α, γ). Twenty fish were analyzed using gas chromatography-mass spectrometry for DP and PBDE, and using liquid chromatography-tandem mass spectrometry for HBCD. DP was detected in 18 samples and ∑DP concentrations were <0.2-14.2 pg g(-1)wet wt. Among the DP isomers, anti-DP was the dominant residue observed in this study. PBDE was detected in all samples. Concentrations of ∑PBDE ranged from 2.2 to 878 pg g(-1) wet wt. HBCD was detected in 18 samples, and ∑HBCD concentrations were <0.02-21.9 ng g(-1)wet wt. In fish landed near the East China Sea and the Sea of Japan, we detected relatively high concentrations of DP, PBDE, and HBCD. These results indicate that the seawaters around East Asia are contaminated with flame retardants. This study demonstrates the presence of DP in fish marketed in Japan for the first time.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Kakimoto K,Nagayoshi H,Yoshida J,Akutsu K,Konishi Y,Toriba A,Hayakawa K

doi

10.1016/j.chemosphere.2012.05.072

subject

Has Abstract

pub_date

2012-10-01 00:00:00

pages

416-9

issue

4

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(12)00693-5

journal_volume

89

pub_type

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