Abstract:
:Fish samples purchased from Japanese markets were analyzed for Dechlorane Plus (DP)(syn-, anti-), polybrominated diphenyl ether (PBDE), and hexabromocyclododecane (HBCD)(α, γ). Twenty fish were analyzed using gas chromatography-mass spectrometry for DP and PBDE, and using liquid chromatography-tandem mass spectrometry for HBCD. DP was detected in 18 samples and ∑DP concentrations were <0.2-14.2 pg g(-1)wet wt. Among the DP isomers, anti-DP was the dominant residue observed in this study. PBDE was detected in all samples. Concentrations of ∑PBDE ranged from 2.2 to 878 pg g(-1) wet wt. HBCD was detected in 18 samples, and ∑HBCD concentrations were <0.02-21.9 ng g(-1)wet wt. In fish landed near the East China Sea and the Sea of Japan, we detected relatively high concentrations of DP, PBDE, and HBCD. These results indicate that the seawaters around East Asia are contaminated with flame retardants. This study demonstrates the presence of DP in fish marketed in Japan for the first time.
journal_name
Chemospherejournal_title
Chemosphereauthors
Kakimoto K,Nagayoshi H,Yoshida J,Akutsu K,Konishi Y,Toriba A,Hayakawa Kdoi
10.1016/j.chemosphere.2012.05.072subject
Has Abstractpub_date
2012-10-01 00:00:00pages
416-9issue
4eissn
0045-6535issn
1879-1298pii
S0045-6535(12)00693-5journal_volume
89pub_type
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