Formation, characteristics, and applications of environmentally persistent free radicals in biochars: A review.

Abstract:

:Due to abundant biomass and eco-friendliness, biochar is exemplified as one of the most promising candidates to mediate the degradation of environmental contaminants. Recently, environmentally persistent free radicals (EPFRs) have been detected in biochars, which can activate S2O82- or H2O2 to generate reactive oxygen species for effective degradation of organic and inorganic contaminants. Comprehending the formation mechanisms of EPFRs in biochars and their interactions with contaminants is indispensable to further develop their environmental applications, e.g., direct and indirect EPFR-mediated removal of organics/inorganics by biochars. With reference to the information of EPFRs in environmental matrices, this article critically reviews the formation mechanisms, characteristics, interactions, and environmental applications of EPFRs in biochars. Synthesis conditions and loading of metals/organics are considered as key parameters controlling their concentrations, types, and activities. This review provides new and important insights into the fate and emerging applications of surface-bound EPFRs in biochars.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Ruan X,Sun Y,Du W,Tang Y,Liu Q,Zhang Z,Doherty W,Frost RL,Qian G,Tsang DCW

doi

10.1016/j.biortech.2019.02.105

subject

Has Abstract

pub_date

2019-06-01 00:00:00

pages

457-468

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(19)30313-X

journal_volume

281

pub_type

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