Can rainwater induce Fenton-driven degradation of herbicides in natural waters?

Abstract:

:Microcosm experiments were conducted to examine Fenton reaction-driven degradation of three common herbicides exposed to a variety of Fe(2+)-H2O2 combinations that are likely to be encountered in natural water environments. The results show that these combinations had significant (P<0.05) effects on removing the water-borne herbicides. This discovery sheds some light on the possible role of rainwater-borne H2O2 in inducing Fenton reaction in many natural waters such as lakes, streams, estuaries and tidal zones, fishponds and paddy fields that may contain ferrous ion at micromolar levels. The research findings obtained from this preliminary work provide a rationale for undertaking further study to confirm the presence of an overlooked naturally-occurring process that may lead to rapid dissipation of many herbicides and other organic pollutants in open water environments. Our immediate follow-up work is to continue the laboratory-scale investigations under more complex experimental conditions, including the uses of various natural water samples for the experiments. This will provide a basis for future field-based study.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Qin J,Li H,Lin C,Chen G

doi

10.1016/j.chemosphere.2013.03.003

subject

Has Abstract

pub_date

2013-08-01 00:00:00

pages

1048-52

issue

8

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(13)00376-7

journal_volume

92

pub_type

杂志文章
  • Toxicity of copper in an oxic stream sediment receiving aquaculture effluent.

    abstract::Sediments were collected from a stream (upstream, outfall and downstream) receiving copper laden catfish pond effluent to assess toxicity to non-target biota. No significant reduction in Hyalella azteca survival or growth (10 d), or Typha latifolia germination and root and shoot growth (7 d) were observed after exposu...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/s0045-6535(00)00354-4

    authors: Huggett DB,Schlenk D,Griffin BR

    更新日期:2001-07-01 00:00:00

  • Towards an improved understanding of processes controlling absorption efficiency and biomagnification of organic chemicals by fish.

    abstract::Dietary exposure is considered the dominant pathway for fish exposed to persistent, hydrophobic chemicals in the environment. Here we present a dynamic, fugacity-based three-compartment bioaccumulation model that describes the fish body as one compartment and the gastrointestinal tract (GIT) as two compartments. The m...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2015.05.053

    authors: Xiao R,Arnot JA,MacLeod M

    更新日期:2015-11-01 00:00:00

  • The differences in phenolic content in rivers exposed and non-exposed to anthropogenic contamination.

    abstract::The purpose of the work was to determine the differences in a kind, number and concentrations of phenol, chlorophenols, chlorocatechols chlorinated methoxyphenols (chloroguaiacols, chlorosyringols) and 3,4,5-trichloroveratrole in the drainage of the Dzierzazna river, the flow non-exposed to anthropogenic contamination...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2007.10.017

    authors: Michałowicz J,Bukowska B,Duda W

    更新日期:2008-03-01 00:00:00

  • Bi4O5I2/nitrogen-doped hierarchical carbon (NHC) composites with tremella-like structure for high photocatalytic performance.

    abstract::BiOI is a visible photocatalyst towards organic pollutant. In this work, biomass waste (withered typha grass) was used to fabricate nitrogen-doped hierarchical carbon (NHC) by an one-step carbonization route. Then NHC provided a good carrier to load the BiOI semiconductor materials by a green simple co-precipitation m...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.05.043

    authors: Jiang T,Jin J,Hou J,Tahir M,Idrees F

    更新日期:2019-08-01 00:00:00

  • Splenocyte apoptotic pathway in mice following oral exposure to cerium trichloride.

    abstract::With their widespread application in agriculture, industry, culture, medicine, and daily life, lanthanide compounds are being brought into the ecological environment and human body through food chains. It is important to know the acute and chronic effects of lanthanides on the environment, nature balance, and the huma...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2010.12.013

    authors: Cheng J,Li N,Cheng Z,Hua R,Cai J,Si W,Hong F

    更新日期:2011-04-01 00:00:00

  • Organochlorine pesticides contamination in agricultural soils of southern Iran.

    abstract::There is limited information about pesticide contamination in Iran's agricultural land, particularly in plains producing exportable fruits. The aim of this investigation was to evaluate the concentration of organochlorine pesticides (OCPs) including hexachlorocyclohexane (HCH), heptachlor, dichloro-diphenyl-trichloroe...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.124983

    authors: Kafaei R,Arfaeinia H,Savari A,Mahmoodi M,Rezaei M,Rayani M,Sorial GA,Fattahi N,Ramavandi B

    更新日期:2020-02-01 00:00:00

  • Spectroscopic characterization of dissolved organic matter and its interactions with metals in surface waters using size exclusion chromatography.

    abstract::HPLC-size exclusion chromatography (SEC), coupled with on-line detection of UV absorbance (UVA) and fluorescence, was used to characterize dissolved organic matter (DOM) and its interactions with dissolved metals in a forest stream, a reservoir, and an urban river. Optimization of eluent concentration (20 mM) allowed ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2009.07.054

    authors: Park JH

    更新日期:2009-10-01 00:00:00

  • Combined fluorescent measurements, parallel factor analysis and GC-mass spectrometry in evaluating the photodegradation of PAHS in freshwater systems.

    abstract::To better understand the transformation and photochemical fate of PAHs in aquatic environments, a custom-designed closed-circuit recirculation photodegradation system, combined with inline semi-continuous fluorescence and absorbance measurements, as well as modelling of excitation-emission (EEM) measurements with para...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.129386

    authors: Seopela MP,Powers LC,Clark C,Heyes A,Gonsior M

    更新日期:2020-12-21 00:00:00

  • Genetic susceptibility to nickel-induced acute lung injury.

    abstract::Human exposure to insoluble and soluble nickel compounds is extensive. Besides wide usage in many industries, nickel compounds are contained in cigarette smoke and, in low levels, in ambient particulate matter. Soluble nickel particulate, especially nickel sulfate (NiSO(4)), has been associated with acute lung injury....

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/S0045-6535(02)00710-5

    authors: Prows DR,McDowell SA,Aronow BJ,Leikauf GD

    更新日期:2003-06-01 00:00:00

  • NLRP3 inflammasome-mediated endothelial cells pyroptosis is involved in decabromodiphenyl ethane-induced vascular endothelial injury.

    abstract::Decabromodiphenyl ethane (DBDPE) is a novel environmental pollutant that has attracted growing attention. Previous studies have indicated that DBDPE could induce vascular endothelial injury and cardiovascular damage, but the underlying mechanisms are not well understood. This study was designed to examine the mechanis...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.128867

    authors: Zheng D,Shi Z,Yang M,Liang B,Zhou X,Jing L,Sun Z

    更新日期:2021-03-01 00:00:00

  • Carbon gas production under different electron acceptors in a freshwater marsh soil.

    abstract::Dynamics of carbon (C) gas emission from wetlands influence global C cycling. In many freshwater systems such as Louisiana freshwater marsh, soil contents of NO3(-) and SO4(2-) have increased due to nutrient loading and saltwater intrusion. This could affect C mineralization and the emission of the major greenhouse ga...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2009.03.013

    authors: Dodla SK,Wang JJ,Delaune RD,Breitenbeck G

    更新日期:2009-07-01 00:00:00

  • Natural levels and photo-production rates of hydrogen peroxide (H2O2) in Andean Patagonian aquatic systems: Influence of the dissolved organic matter pool.

    abstract::In aquatic environments the reactive oxygen species hydrogen peroxide (H2O2) is produced through photochemical reactions involving chromophoric dissolved organic matter (CDOM). Andean Patagonian freshwaters experience challenging underwater UV levels, which promote high levels of photochemical weathering. In this inve...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2018.10.179

    authors: García PE,Queimaliños C,Diéguez MC

    更新日期:2019-02-01 00:00:00

  • Removal of PAHs with surfactant-enhanced soil washing: influencing factors and removal effectiveness.

    abstract::PAH removal with surfactant enhanced washing was investigated through a series of laboratory tests to examine the effect of stirring speed, washing time, surfactant concentration, liquid/solid ratio, temperature, and on-and-off mode. The first four factors show significant influence on the PAH removal while the latter...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2010.11.076

    authors: Peng S,Wu W,Chen J

    更新日期:2011-02-01 00:00:00

  • Entrapped cells-based-anaerobic membrane bioreactor treating domestic wastewater: Performances, fouling, and bacterial community structure.

    abstract::A laboratory scale study on treatment performances and fouling of entrapped cells-based-anaerobic membrane bioreactor (E-AnMBR) in comparison with suspended cells-based-bioreactor (S-AnMBR) treating domestic wastewater was conducted. The difference between E-AnMBR and S-AnMBR was the uses of cells entrapped in phospho...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2017.08.113

    authors: Juntawang C,Rongsayamanont C,Khan E

    更新日期:2017-11-01 00:00:00

  • Cytotoxic, genotoxic and mutagenic effects of sewage sludge on Allium cepa.

    abstract::The objective of this study was to ascertain the cytotoxic, genotoxic and mutagenic potential of sewage sludge using Allium cepa bioassay. Solubilized and crude sludge from two sewage treatment stations (STSs), herein named JM and M, were tested. In addition, sanitized, crude and solubilized sludge were also analyzed ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2016.01.071

    authors: Corrêa Martins MN,de Souza VV,da Silva Souza T

    更新日期:2016-04-01 00:00:00

  • Electrochemical oxidation of 2,4,5-trichlorophenoxyacetic acid by metal-oxide-coated Ti electrodes.

    abstract::Electrochemical oxidation of 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) over metal-oxide-coated Ti anodes, i.e., Ti/SnO2-Sb/Ce-PbO2, Ti/SnO2-Sb and Ti/RuO2, was examined. The degradation efficiency of over 90% was attained at 20 min at different initial concentrations (0.5-20 mg L(-1)) and initial pH values (3.1-11.2...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2015.04.100

    authors: Maharana D,Xu Z,Niu J,Rao NN

    更新日期:2015-10-01 00:00:00

  • Histopathological changes and lipid metabolism in the liver of Bufo gargarizans tadpoles exposed to Triclosan.

    abstract::In the current study, the adverse effects of TCS on liver health of B. gargarizans tadpoles were assessed. B. gargarizans larvae were exposed to TCS at 0, 10, 30, 60, and 150 μg L-1 from Gosner stage 3 until metamorphic climax. The hepatosomatic index (HSI), hepatic histological and ultrastructural features, and trans...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2017.05.040

    authors: Chai L,Chen A,Luo P,Zhao H,Wang H

    更新日期:2017-09-01 00:00:00

  • Sedimentary biomarkers along a contamination gradient in a human-impacted sub-estuary in Southern Brazil: a multi-parameter approach based on spatial and seasonal variability.

    abstract::The composition and seasonal variations of sedimentary organic matter were investigated along the Cotinga sub-estuary, located in Paranaguá Bay, a large South American estuary where urban activities and the primary Brazilian grain shipping port are sources of pollution. Steroids and hydrocarbons were analyzed in surfa...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2013.11.052

    authors: de Abreu-Mota MA,de Moura Barboza CA,Bícego MC,Martins CC

    更新日期:2014-05-01 00:00:00

  • Waste green sands as reactive media for the removal of zinc from water.

    abstract::Waste green sands are industrial byproducts of the gray iron foundry industry. These green sands are composed of fine silica sand, clay binder, organic carbon, and residual iron particles. Because of their potential sorptive and reactive properties, tests were performed to determine the feasibility of using green sand...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2004.04.037

    authors: Lee T,Park JW,Lee JH

    更新日期:2004-08-01 00:00:00

  • QSARs for the aquatic toxicity of aromatic aldehydes from Tetrahymena data.

    abstract::The aim of the study was to develop quantitative structure-activity relationships (QSARs) for a large group of 77 aromatic aldehydes tested for acute toxicity to the ciliate Tetrahymena pyriformis using mechanistically interpretable descriptors. The resulting QSARs revealed that the 1-octanol/water partition coefficie...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2005.04.040

    authors: Netzeva TI,Schultz TW

    更新日期:2005-12-01 00:00:00

  • Study on the preparation of the hierarchical porous CX-TiO2 composites and their selective degradation of PHE solubilized in soil washing eluent.

    abstract::A series of CX-TiO2(Carbon Xerogel- TiO2) composites with a hierarchical porous structure were obtained through the sol-gel method followed by drying and carbonization, and have been applied to treating solubilizing wastewater containing a high concentration of phenanthrene (PHE). The characterizations demonstrated th...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.127588

    authors: Wang A,Peng X,Shi N,Lu X,Yang C,He P,Wu Y

    更新日期:2020-12-01 00:00:00

  • Preparation of Fe@Fe2O3/3D graphene composite cathode for electrochemical removal of sulfasalazine.

    abstract::In the present study, heterogeneous electro-Fenton (EF) process was applied to remove the sulfasalazine (SU) pharmaceutical from aqueous solutions. In the first part, 3D graphene loaded with Fe@Fe2O3 core-shell nanowires (Fe@Fe2O3/3D-GO) was used as a cathode electrode in the EF process. Graphene oxide (GO) was synthe...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2020.128581

    authors: Amali S,Zarei M,Ebratkhahan M,Khataee A

    更新日期:2020-10-09 00:00:00

  • Mobility of rare earth elements in mine drainage: Influence of iron oxides, carbonates, and phosphates.

    abstract::The geochemical behavior of rare earth elements (REE) was investigated using weathering cells. The influence of sorption and precipitation on dissolved REE mobility and fractionation is evaluated using synthetic iron-oxides, carbonates, and phosphates. Sorption cell tests are conducted on the main lithologies of the e...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2018.02.054

    authors: Edahbi M,Plante B,Benzaazoua M,Ward M,Pelletier M

    更新日期:2018-05-01 00:00:00

  • A novel sequential process for remediating rare-earth wastewater.

    abstract::A novel and economic sequential process consisting of precipitation, adsorption, and oxidation was developed to remediate actual rare-earth (RE) wastewater containing various toxic pollutants, including radioactive species. In the precipitation step, porous air stones (PAS) containing waste oyster shell (WOS), PASWOS,...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2015.10.107

    authors: Cui M,Jang M,Kang K,Kim D,Snyder SA,Khim J

    更新日期:2016-02-01 00:00:00

  • Human exposure to toxic metals via contaminated dust: Bio-accumulation trends and their potential risk estimation.

    abstract::We assessed the levels of potentially toxic trace metals, Zinc (Zn), Lead (Pb), Manganese (Mn), Copper (Cu), Nickel (Ni), Chromium (Cr), Cobalt (Co), and Cadmium (Cd), in dust, hair, nail and serum, sampled in rural, urban and industrial areas of Punjab, Pakistan. Trace metals occurrence in all samples, in descending ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2015.03.004

    authors: Mohmand J,Eqani SA,Fasola M,Alamdar A,Mustafa I,Ali N,Liu L,Peng S,Shen H

    更新日期:2015-08-01 00:00:00

  • Heterogeneous water phase catalysis as an environmental application: a review.

    abstract::Catalytic water phase processes as an environmental application is a relatively novel subject with tremendous potential in the near future. This review of 120 references presents the wide scale of heterogeneous water phase applications studied mainly within past five years. Both oxidation and hydrogenation processes a...

    journal_title:Chemosphere

    pub_type: 杂志文章,评审

    doi:10.1016/s0045-6535(02)00168-6

    authors: Pirkanniemi K,Sillanpää M

    更新日期:2002-09-01 00:00:00

  • TiO2 photocatalytic degradation of PCBs in soil-water systems containing fluoro surfactant.

    abstract::Titanium dioxide-mediated photodegradation of Polychlorinated biphenyls (PCBs) in soil/aqueous systems with added fluorinated surfactant was investigated. PCBs can bind tightly to organic matter in the soil, especially in aged, contaminated soil. Experiments showed an effective PCB photocatalytic degradation in mixed ...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/s0045-6535(99)00492-0

    authors: Huang Q,Hong CS

    更新日期:2000-09-01 00:00:00

  • Activation of peroxydisulfate by nanoscale zero-valent iron for sulfamethoxazole removal in agricultural soil: Effect, mechanism and ecotoxicity.

    abstract::In this study, peroxydisulfate (PDS) was successfully activated by nanoscale zero-valent iron (nZVI) for the degradation of sulfamethoxazole (SMX, antibiotic frequently detected in the environment) in agricultural soils. The results indicated that the degradation of SMX was affected by the nZVI dose, the ratio of SMX/...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/j.chemosphere.2019.02.074

    authors: Zhou Z,Ma J,Liu X,Lin C,Sun K,Zhang H,Li X,Fan G

    更新日期:2019-05-01 00:00:00

  • Soil-mediated prion transmission: is local soil-type a key determinant of prion disease incidence?

    abstract::Prion diseases, including chronic wasting disease (CWD) and scrapie, can be transmitted via indirect environmental routes. Animals habitually ingest soil, and results from laboratory experiments demonstrate prions can bind to a wide range of soils and soil minerals, retain the ability to replicate, and remain infectio...

    journal_title:Chemosphere

    pub_type: 杂志文章,评审

    doi:10.1016/j.chemosphere.2011.12.076

    authors: Saunders SE,Bartz JC,Bartelt-Hunt SL

    更新日期:2012-05-01 00:00:00

  • 32P-postlabeling analysis of aromatic DNA-adducts in liver and brain of wild brook trout (Salvelinus fontinalis).

    abstract::Several studies have reported the absence of DNA-adducts in fish collected from unpolluted areas. We determined DNA-adduct levels in liver and brain tissue of wild brook trout (Salvelinus fontinalis) from remote areas of Newfoundland and sub-arctic Labrador, that have no known input of anthropogenic contamination. Var...

    journal_title:Chemosphere

    pub_type: 杂志文章

    doi:10.1016/0045-6535(94)00441-v

    authors: Ray S,Bieger T,Scruton DA

    更新日期:1995-02-01 00:00:00