Abstract:
:This study aims to prepare environmentally friendly iron catalysts supported on silica, using glycerol as green reducing and stabilizing agent, for application in heterogeneous Fenton degradation of the pollutant dye methyl orange (MO). The catalysts were characterized by X-ray powder diffraction, atomic absorption spectroscopy, scanning electron microscopy, transmission electron microscopy, thermogravimetric analyses, Mössbauer and Fourier transform infrared spectroscopies, which revealed the formation of iron(II)/(III) oxalates from the oxidation of glycerol by the iron(III) nitrate precursor. Besides, iron oxihydroxide nanoparticles with superparamagnetic behavior were also formed. Iron catalysts prepared in the presence of nickel(II) or zinc(II) nitrates lead to the formation of the corresponding oxalates. The catalysts were able to degrade MO, efficiently in 180 min of reaction. Fe/SiO2 furnished higher reaction rates, followed by Zn4Fe2/SiO2, which presented higher iron content as well as the smallest nanoparticles. Reaction parameters such as catalyst dosage, hydrogen peroxide concentration, pH and reaction temperature were investigated.
journal_name
Environ Technoljournal_title
Environmental technologyauthors
Trotte NSF,Alzamora M,Sánchez DR,Carvalho NMFdoi
10.1080/09593330.2017.1367038subject
Has Abstractpub_date
2018-11-01 00:00:00pages
2822-2833issue
21eissn
0959-3330issn
1479-487Xjournal_volume
39pub_type
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