The recycling of incinerated sewage sludge ash as a raw material for CaO-Al2O3-SiO2-P2O5 glass-ceramic production.

Abstract:

:In this paper, the recycling of incinerated sewage sludge ash (ISSA) into glass-ceramic materials by a two-stage sintering cycle of nucleation stage and crystallization stage without any pressure and binder is presented. The parent glasses were subjected to the following nucleation/crystallization temperature and time level: (A) 790°C, 1.0 h/870°C, 1.0-3.0 h; (B) 790°C, 1.0 h/945°C, 1.0-3.0 h and (C) 790°C, 1.0 h/1065°C, 1.0-3.0 h. X-ray power diffraction analysis results revealed that multiple crystalline phases coexisted in the glass-ceramic materials and the crystalline phase compositions were more affected by crystallization temperature than crystallization time. Scanning electron microscopy analysis showed an interlocking microstructure of glass phases and crystals with different sizes and spatial distribution. The glass-ceramics crystallized at 945°C for 2.0 h exhibited optimal properties of density of 2.88±0.08 g/cm3, compression strength of 247±12 MPa, bending strength of 118±14 MPa and water absorption of 0.42±0.04. The leaching concentrations of heavy metals were far lower than the limits required by the regulatory standard of EPA. This paper provides a feasible, low-cost and promising method to produce ISSA-based glass-ceramics and highlights the principal characteristics that must be taken into account to use ISSA correctly in glass-ceramics.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Zhang Z,Zhang L,Yin Y,Liang X,Li A

doi

10.1080/09593330.2014.982208

subject

Has Abstract

pub_date

2015-05-01 00:00:00

pages

1098-103

issue

9-12

eissn

0959-3330

issn

1479-487X

journal_volume

36

pub_type

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