Effects of Mo(VI) on phototrophic hydrogen production by Rhodobacter sphaeroides.

Abstract:

:Effects of Mo(6+) concentration on phototrophic hydrogen production of Rhodobacter sphaeroides were investigated using lactate as the sole carbon source. Results showed that an increase of Mo(6+) from nil to 1000 microg l(-1) led to increases in hydrogen yield, maximum production rate, conversion efficiency, biomass yield and lactate removal. At 100 microg-Mo l(-1), the maximum rate was 12.0 ml h(-1) with a conversion efficiency of 36.1%, the cell yields were 1.11 g-cell g(-1) -lactate and 2.4 g-cell g(-1)-TOC removed. Further increase of Mo(6+) improved hydrogen production only marginally. Degradation of lactate by R. sphaeroides produced not just hydrogen but also acetate, butyrate, i-valerate, i-caproate, hexanoate and some unidentified organic intermediates, but did not produce propionate and alcohols. Nitrogenase activity, as measured by the acetylene reduction method, had no clear correlation with either Mo(6+) concentration or hydrogen yield.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Fang HH,Li RY,Zhang T

doi

10.1080/09593330.2010.535176

subject

Has Abstract

pub_date

2011-08-01 00:00:00

pages

1279-85

issue

11-12

eissn

0959-3330

issn

1479-487X

journal_volume

32

pub_type

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