Copper ferrocyanide chemically immobilized onto a polyvinylidene fluoride hollow-fibre membrane surface for the removal of aqueous cesium.

Abstract:

:A method of chemically bonding copper ferrocynide (CuFC) to the surface of a PVDF hollow-fibre membrane (PVDF-CuFC) was designed and the resulting PVDF-CuFC was applied to the effective removal of aqueous cesium (Cs). In order to chemically immobilize CuFC on the surface of the PVDF hollow-fibre membrane, carboxyl groups were introduced onto the membrane surface (PVDF-COOH) to peptide bond with amine groups from CuFC. The introduction of the carboxyl group onto the surface of the PVDF hollow-fibre membrane was confirmed by Fourier-transform infrared spectroscopy (FT-IR), while the immobilization of CuFC was confirmed by scanning electron microscopy with energy dispersed spectroscopy, FT-IR, and thermogravimetric analysis. The PVDF-CuFC showed higher Cs adsorption kinetics and adsorption capacity than PVDF-COOH. Moreover, as the initial pH increased, the amount of Cs adsorption by PVDF-CuFC also increased. However, the amount of Cs adsorption at pH 10 was slightly less. The applicability of PVDF-CuFC as a filter type adsorbent for the treatment of a Cs-contaminated water source is demonstrated by continuous filtration experiments.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Lee HK,Choi SJ

doi

10.1080/09593330.2021.1871659

subject

Has Abstract

pub_date

2021-01-28 00:00:00

pages

1-11

eissn

0959-3330

issn

1479-487X

pub_type

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