Abstract:
:A method of chemically bonding copper ferrocynide (CuFC) to the surface of a PVDF hollow-fibre membrane (PVDF-CuFC) was designed and the resulting PVDF-CuFC was applied to the effective removal of aqueous cesium (Cs). In order to chemically immobilize CuFC on the surface of the PVDF hollow-fibre membrane, carboxyl groups were introduced onto the membrane surface (PVDF-COOH) to peptide bond with amine groups from CuFC. The introduction of the carboxyl group onto the surface of the PVDF hollow-fibre membrane was confirmed by Fourier-transform infrared spectroscopy (FT-IR), while the immobilization of CuFC was confirmed by scanning electron microscopy with energy dispersed spectroscopy, FT-IR, and thermogravimetric analysis. The PVDF-CuFC showed higher Cs adsorption kinetics and adsorption capacity than PVDF-COOH. Moreover, as the initial pH increased, the amount of Cs adsorption by PVDF-CuFC also increased. However, the amount of Cs adsorption at pH 10 was slightly less. The applicability of PVDF-CuFC as a filter type adsorbent for the treatment of a Cs-contaminated water source is demonstrated by continuous filtration experiments.
journal_name
Environ Technoljournal_title
Environmental technologyauthors
Lee HK,Choi SJdoi
10.1080/09593330.2021.1871659subject
Has Abstractpub_date
2021-01-28 00:00:00pages
1-11eissn
0959-3330issn
1479-487Xpub_type
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