Abstract:
:This work reports the experimental determination of relevant thermophysical properties of five halogenated fluorenes. The vapor pressures of the compounds studied were measured at different temperatures using two different experimental techniques. The static method was used for studying 2-fluorofluorene (liquid and crystal vapor pressures between 321.04 K and 411.88 K), 2-iodofluorene (liquid and crystal vapor pressures between 362.63 K and 413.86 K), and 2,7-dichlorofluorene (crystal vapor pressures between 364.64 K and 394.22 K). The Knudsen effusion method was employed to determine the vapor pressures of 2,7-difluorofluorene (crystal vapor pressures between 299.17 K and 321.19 K), 2,7-diiodofluorene (crystal vapor pressures between 393.19 K and 415.14 K), and (again) 2-iodofluorene (crystal vapor pressures between 341.16 K and 361.12 K). The temperatures and the molar enthalpies of fusion of the five compounds were determined using differential scanning calorimetry. The application to halogenated fluorenes of recently developed methods for predicting vapor pressures and enthalpies of sublimation and vaporization of substituted benzenes is also discussed.
journal_name
Chemospherejournal_title
Chemosphereauthors
Oliveira JA,Oliveira TS,Gaspar A,Borges F,Ribeiro da Silva MD,Monte MJdoi
10.1016/j.chemosphere.2016.05.014subject
Has Abstractpub_date
2016-08-01 00:00:00pages
25-32eissn
0045-6535issn
1879-1298pii
S0045-6535(16)30643-9journal_volume
157pub_type
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