Study on the volatility of halogenated fluorenes.

Abstract:

:This work reports the experimental determination of relevant thermophysical properties of five halogenated fluorenes. The vapor pressures of the compounds studied were measured at different temperatures using two different experimental techniques. The static method was used for studying 2-fluorofluorene (liquid and crystal vapor pressures between 321.04 K and 411.88 K), 2-iodofluorene (liquid and crystal vapor pressures between 362.63 K and 413.86 K), and 2,7-dichlorofluorene (crystal vapor pressures between 364.64 K and 394.22 K). The Knudsen effusion method was employed to determine the vapor pressures of 2,7-difluorofluorene (crystal vapor pressures between 299.17 K and 321.19 K), 2,7-diiodofluorene (crystal vapor pressures between 393.19 K and 415.14 K), and (again) 2-iodofluorene (crystal vapor pressures between 341.16 K and 361.12 K). The temperatures and the molar enthalpies of fusion of the five compounds were determined using differential scanning calorimetry. The application to halogenated fluorenes of recently developed methods for predicting vapor pressures and enthalpies of sublimation and vaporization of substituted benzenes is also discussed.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Oliveira JA,Oliveira TS,Gaspar A,Borges F,Ribeiro da Silva MD,Monte MJ

doi

10.1016/j.chemosphere.2016.05.014

subject

Has Abstract

pub_date

2016-08-01 00:00:00

pages

25-32

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(16)30643-9

journal_volume

157

pub_type

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