Chemical extraction of trace elements from hazardous fine fraction at an old glasswork dump.

Abstract:

:Old glassworks sites have been always associated with contamination by different trace elements like Pb, Cd, As, Zn and others. The mixture of soil and waste glass of particle sizes <2 mm at one of the oldest Swedish glassworks (the Pukeberg) was studied by analyzing the trace elements content, organic content (3.6%) and pH (7.4). The results showed hazardous concentrations of Pb (1525 mg/kg), Ba (1312 mg/kg), Sb (128 mg/kg), Cd (36 mg/kg), As (118 mg/kg), Zn (1154 mg/kg) and Co (263 mg/kg) exceeded the Swedish guidelines of contaminated soil. Batch chemical extraction by the chelating agents EDTA, DTPA and the biodegradable NTA were performed to study the effect of chelating agent concentration and mixing time on the extraction efficiencies by following a Box-Wilson design of experiments. The results displayed good extraction efficiencies (less than 41%) of Pb, Cd, As and Zn by the EDTA, DTPA and NTA, which seemed depends on the type of chelator. In addition, high correlation between the extraction efficiencies, the chelators concentration and mixing time was found based on the statistical and experimental results.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Jani Y,Hogland W

doi

10.1016/j.chemosphere.2017.12.142

subject

Has Abstract

pub_date

2018-03-01 00:00:00

pages

825-830

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(17)32120-3

journal_volume

195

pub_type

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