Abstract:
:In the present study, the macroscopic sorption behaviors and microscopic immobilization mechanisms of Ni(II) at cryptomelane/water interfaces were explored using the combination of batch sorption technique, desorption procedure, theoretical simulation, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and extended X-ray absorption fine structure (EXAFS) analyses. The good simulation of the pseudo-second-order model on the sorption kinetics data suggests a driving force of chemical sorption rather than mass transport or physical interaction. The sorption trends and uptake mechanisms are obviously related to the solution pH, with cation exchange or outer-sphere surface complexation at an acidic pH of 4.0, inner-sphere surface complexation in both the edge-shared (ES) and double corner-shared (DCS) modes at a neutral pH of 7.0, and precipitation of α-Ni(OH)2(s) phase at a highly alkaline pH of 10.0. The gradual increase of Ni(II) sorption amount with solution temperature rising from 293 K to 333 K is consistent with the increased ratio of the weak DCS configuration. The research findings herein can help us better understand the migration and transformation trends of Ni(II) in the manganese mineral-riched aquatic environment.
journal_name
Chemospherejournal_title
Chemosphereauthors
Wu C,Chen L,Yang S,Cai Y,Xu L,Wu X,Qin H,Liu Z,Chen L,Wang Sdoi
10.1016/j.chemosphere.2018.07.029subject
Has Abstractpub_date
2018-11-01 00:00:00pages
392-400eissn
0045-6535issn
1879-1298pii
S0045-6535(18)31287-6journal_volume
210pub_type
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