Adsorption and mechanistic study for phosphate removal by magnetic Fe3O4-doped spent FCC catalysts adsorbent.

Abstract:

:The waste materials utilization has attained increasing attention due to the generation of a large number of spent materials. In the current study, a practical magnetic adsorbent (Fe3O4-doped spent Fluid Catalytic Cracking catalysts, abbreviated as FCCx@(Fe)y-O) was prepared, liable to be separated. The batch experiments were employed to investigate the phosphate removal behavior. The findings of this study demonstrated that FCC4@(Fe)1-O exhibited the best phosphate removal performance among the adsorbents (FCCx@(Fe)y-O), attributed to rough surface layer, i.e., composed of active sites. The various characterizations results revealed that the adsorption behavior of FCC4@(Fe)1-O followed the inner-sphere adsorption based on ligand exchanges mechanism. Furthermore, OH- played an important role in the adsorption process. Minor effects were showed on the phosphate removal in the experiments of commonly coexisting anions, except CO32- and SiO32-. The above findings affirmed that FCC4@(Fe)1-O was a suitable adsorbent for phosphate removal in the practical application.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Yuan L,Qiu Z,Yuan L,Tariq M,Lu Y,Yang J,Li Z,Lyu S

doi

10.1016/j.chemosphere.2018.11.132

subject

Has Abstract

pub_date

2019-03-01 00:00:00

pages

183-190

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(18)32239-2

journal_volume

219

pub_type

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