Abstract:
:In humans the main route of exposure to toxic metals is through the diet, and there is therefore a clear need for this source of contamination to be minimized, particularly in food of animal origin. For this purpose, the various sources of toxic metals in livestock farming (which vary depending on the production system) must be taken into account. The objectives of the present study were to establish the profile of metal exposure in dairy cattle in Spain and to determine, by chemometric (multivariate statistical) analysis, any differences between organic and conventional systems. Blood samples from 522 cows (341 from organic farms and 181 from conventional farms) were analysed by inductively coupled plasma mass spectrometry to determine the concentrations of 14 elements: As, Cd, Co, Cr, Cu, Fe, Hg, I, Mn, Mo, Ni, Pb, Se and Zn. In conventional systems the generally high and balanced trace element concentrations in the mineral-supplemented concentrate feed strongly determined the metal status of the cattle. However, in organic systems, soil ingestion was an important contributing factor. Our results demonstrate that general information about the effects of mineral supplementation in conventional farming cannot be directly extrapolated to organic farming and special attention should be given to the contribution of ingestion of soil during grazing and/or ingestion of soil contaminated forage.
journal_name
Chemospherejournal_title
Chemosphereauthors
López-Alonso M,Rey-Crespo F,Herrero-Latorre C,Miranda Mdoi
10.1016/j.chemosphere.2017.07.112subject
Has Abstractpub_date
2017-10-01 00:00:00pages
1048-1055eissn
0045-6535issn
1879-1298pii
S0045-6535(17)31126-8journal_volume
185pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::Dioxins (PCDD + PCDF) and polychlorinated biphenyl (PCB) are potentially hazardous compounds and have structural similarity to thyroid hormones. Our research group on "Dioxins and PCB in Human Milk" was organized in 1997 and has been active for the past three years. We collected breast milk from 80 mothers living in T...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(01)00050-9
更新日期:2001-12-01 00:00:00
abstract::This study investigates the level of organochlorine pesticides in the raw food from open markets in Kinshasa, Democratic Republic of Congo (DRC), and Johannesburg, South Africa. It assesses the potential health risks associated with the organochlorine pesticide residues. The Quick, Easy, Cheap, Effective, Rugged, and ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.08.055
更新日期:2016-12-01 00:00:00
abstract::Environmental biotechnology is the use of biotechnology to develop and regulate biological systems for the remediation of environmental contamination. Nature has gifted ample material for remediation of its resources, among which chitosan is one of the most important and largely available biomaterial globally. Chitosa...
journal_title:Chemosphere
pub_type: 杂志文章,评审
doi:10.1016/j.chemosphere.2020.128934
更新日期:2021-03-01 00:00:00
abstract::Degradation of hydrofluoro-olefins (HFOs) with oxidants plays a significant role in the troposphere. Thus, we have investigated detail theoretical calculations of hydroxyl radical (•OH) initiated oxidation of 2-fluoropropene (CH3CFCH2) using M06-2X/6-311++G(d,p) level of theory. Here, we have considered different poss...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.124556
更新日期:2020-01-01 00:00:00
abstract::Soil contamination can be one path for streams and groundwater contamination. As a complement of chemical analysis and total contaminants determination, bioassays can provide information on the bioavailable fraction of chemical compounds, focusing on the retention and habitat function of soils. In this study the evalu...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.02.070
更新日期:2005-10-01 00:00:00
abstract::The widespread occurrence of synthetic antibiotic sulfamethoxazole (SMX)- poses a potential risk to aquatic ecosystems where dissolved organic matter (DOM) may affect its photolysis. In this study, the elimination of SMX by solar photolysis was investigated in the presence of leonardite humic acid (LHA) and its fracti...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.125642
更新日期:2020-05-01 00:00:00
abstract::The QWASI fugacity mass balance model has been widely used since 1983 for both scientific and regulatory purposes to estimate the concentrations of organic chemicals in water and sediment, given an assumed rate of chemical emission, advective inflow in water or deposition from the atmosphere. It has become apparent th...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.04.033
更新日期:2014-09-01 00:00:00
abstract::In vitro fertilization (IVF) is one of the most important treatments of infertility to provide a chance of conceiving. In IVF treatment, sperm are washed and motile sperm are isolated with sperm washing media (SWM) for the purpose of fertilization; fertilized ova are then incubated for a maximum of 5 or 6d in media fo...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2011.09.043
更新日期:2012-02-01 00:00:00
abstract::Although the use of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) has been prohibited in Singapore since 1980, OCPs and PCBs still can be detected in the environment and represent a potential threat to public health. In this study, OCPs and PCBs were measured in house dust samples collected fro...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2007.03.051
更新日期:2007-08-01 00:00:00
abstract::Mechanical soil aeration has long been regarded as an effective ex-situ remediation technique and as suitable for remediation of large-scale sites contaminated by volatile organic compounds (VOCs) at low cost. However, it has been reported that the removal efficiency of VOCs from soil is relatively low in the late sta...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.10.074
更新日期:2015-02-01 00:00:00
abstract::The speciation of Al3+ in aqueous solutions containing organic and inorganic ligands important from a biological (citrate (Cit3-), gluconate (Gluc-), lactate (Lac-), silicate (H2SiO42-), carbonate (CO32-), fluoride (F-)) and industrial (Gantrez®; polymethyl-vinyl-ether-co-maleic acids; GTZ S95 and GTZ AN169) point of ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.08.015
更新日期:2017-11-01 00:00:00
abstract::Landfill leachate is a typical refractory wastewater for which research into rapid and efficient treatment methods has become very topical. In this study, a coagulation-ozonation process was developed to treat the concentrate arising from membrane treatment of landfill leachate. The effect of coagulant type and initia...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.11.002
更新日期:2019-02-01 00:00:00
abstract::In this study, we investigated the concentrations of Fukushima nuclear power plant accident (FNPPA)-derived radiocesium (134Cs, 137Cs) deposited in the topsoil of Jeju Island, Korea. We also evaluated the soil inventories of radionuclides and compared the concentrations deposited by rainwater and fallout. We present t...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128457
更新日期:2021-02-01 00:00:00
abstract::Persulfate based advanced oxidation process is a promising technology for refractory contaminants removal. Cobalt is considered as the most efficient metal in catalyzing peroxymonosulfate decomposition. Although different cobalt based nanomaterials have been developed, easy aggregation and metal ion leaching during ca...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.125577
更新日期:2020-04-01 00:00:00
abstract::Currently, exploring effective measures to reduce multiple toxic metals accumulation in rice grains is an urgent issue to be tackled. Pot experiments were thus conducted to explore the effects and mechanisms of foliar spraying with composite sols of silicon (Si) and selenium (Se) during tillering to booting stage on d...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126347
更新日期:2020-07-01 00:00:00
abstract::Iron nanoparticles (Fe NPs) were synthesized herein through a simple and eco-friendly method using FeCl3 and aqueous plant extract (dimocarpus longan, DL). Compared with Fe NPs prepared via traditional chemical methods, this biogenetic DL-Fe NPs demonstrates higher catalytic activity in Fenton-like reaction to degrade...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127618
更新日期:2020-12-01 00:00:00
abstract::This study investigated the acute and sub-acute toxicity responses in zebrafish following their exposure to hydroxyapatite-loaded cadmium nanoparticles (nHAP-Cd). The results indicate that cadmium chloride (Cd2+), 20 nm nHAP-Cd (nHAP20-Cd), and 40 nm nHAP-Cd (nHAP40-Cd) caused toxicity in zebrafish; the toxicity level...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.03.146
更新日期:2018-07-01 00:00:00
abstract::The environmental fate of the tungstate (VI) oxyanion [ e.g. mono tungstate and several polytungstate, generally expressed by W (VI)] is largely controlled by sorption on soil minerals, especially on iron oxide minerals. Molecular scale evaluation of W (VI) retention on iron oxides in the presence of competing oxyanio...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.09.157
更新日期:2018-12-01 00:00:00
abstract::Propylbenzenes (PBZs) and trimethylbenzenes (TMBs) are aromatic hydrocarbon compounds widely used in many industries with potential release to different environments. The fate and aquatic effects of these compounds in the environment were evaluated. Evidence suggests that PBZs and TMBs will rapidly volatilise from wat...
journal_title:Chemosphere
pub_type: 杂志文章,评审
doi:10.1016/j.chemosphere.2020.128533
更新日期:2021-02-01 00:00:00
abstract::Triadimenol is an effective meatabolite derived from the triazole fungicide triadimenfon. It is an agriculturally important reagent of environmentally emerging concern because of its broad use, persistent occurrence in the environment and greater fungicidal or toxic potency than the parent compound. However, the ecoto...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.078
更新日期:2016-06-01 00:00:00
abstract::We investigated whether polychlorinated biphenyls (PCBs) and water could be simultaneously removed from river sediment by solvent extraction using liquefied dimethyl ether (DME) as the extractant. DME exists in a gaseous state at normal temperature and pressure and can dissolve organic substances and some amount of wa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.12.017
更新日期:2010-02-01 00:00:00
abstract::In Sweden fatty fish from the Baltic Sea (at the Swedish east coast) constitute the main exposure route for persistent organochlorine compounds (POC). The present study assessed reproductive outcomes among fishermen's sisters from the Swedish east coast, who were shown to had had a relatively high consumption of conta...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(99)00377-x
更新日期:2000-05-01 00:00:00
abstract::This work describes a rapid and sensitive solid-phase microextraction (SPME) method for the isolation and analysis of methyl tert-butyl ether in water samples. Methyl tert-butyl ether was extracted from aqueous solutions using SPME fibre coated with Divinylbenzene/Carboxen/polydimethylsiloxane (30 microm film thicknes...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00501-4
更新日期:2001-08-01 00:00:00
abstract::Limited literature exists on toxaphene contamination in food worldwide, particularly in mainland China. In this study, three toxaphene congeners, Parlar 26 (B8-1413), Parlar 50 (B9-1679) and Parlar 62 (B9-1025), were analyzed in five different food categories from the Pearl River Delta Area in China using isotope dilu...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.121
更新日期:2016-06-01 00:00:00
abstract::TiO2-encapsulated H-ZSM photocatalysts were prepared by physical mixing of TiO2 and zeolites. Pt was immobilized on the surface of the TiO2-encapsulated zeolite (H-ZSM) catalysts by a simple photochemical reduction method. Different weight ratios of both TiO2 and Pt were hybridized with H-ZSM and the catalytic perform...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.03.063
更新日期:2016-06-01 00:00:00
abstract::Humic substances (HS) including humic acid (HA) and fulvic acid (FA) are ubiquitous in the natural waters. Although numerous studies documented their role in photodegradation of organic pollutants, the competitive effects of photosensitization and light-screening of HS on the photodegradation of pollutants are not yet...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.08.110
更新日期:2017-11-01 00:00:00
abstract::A value of simultaneously extracted metal to acid-volatile sulfide (SEM-AVS) can provide important information regarding metal availability in anaerobic sediment. SEM and AVS concentrations were obtained by the cold-acid purge-and-trap technique during spring and summer at six locations along the Mississippi River flo...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(01)00037-6
更新日期:2001-11-01 00:00:00
abstract::The occurrence and fate of twenty-one pharmaceutically active compounds (PhACs) were investigated in different steps of the largest wastewater treatment plant (WWTP) in Southwest China. Concentrations of these PhACs were determined in both wastewater and sludge phases by a high-performance liquid chromatography couple...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.10.062
更新日期:2014-03-01 00:00:00
abstract::Field monitoring was practiced from 2001 to 2003 to evaluate the input (irrigation, atmospheric deposition, and fertilizer application) and the output (uptake and accumulation into the above-ground biomass of rice plants and leaching) of cadmium (Cd) in a contaminated paddy field in Tokyo. The cadmium concentrations o...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.11.018
更新日期:2007-03-01 00:00:00
abstract::An efficient and inexpensive catalyst for oxygen reduction reaction (ORR), polyaniline (PANI) and β-MnO2 nanocomposites (PANI/β-MnO2), was developed for air-cathode microbial fuel cells (MFCs). The PANI/β-MnO2, β-MnO2, PANI and β-MnO2 mixture modified graphite felt electrodes were fabricated as air-cathodes in double-...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.01.058
更新日期:2018-05-01 00:00:00