Abstract:
:Metal-organic frameworks (MOFs) have been attracting intensive attention because of their commendable potential in many applications. Postsynthetic modification for redesigning chemical characteristics and pore structures can greatly improve performance and expand functionality of MOF materials. Here, we develop a versatile vapor-phase linker exchange (VPLE) methodology for MOF modification. Through solvent-free and environment-friendly VPLE processing, various linker analogs with functional groups but not for straightforward MOF crystallization are inserted into frameworks as daughter building blocks. Besides single exchange for preparing MOFs with dual linkers, VPLE can further be performed by multistage operations to obtain MOF materials with multiple linkers and functional groups. The halogen-incorporated ZIFs exhibit good porosity, tunable molecular affinity, and impressive CO2/N2 and CH4/N2 adsorption selectivities up to 31.1 and 10.8, respectively, which are two to six times higher than those of conventional adsorbents. Moreover, VPLE can substantially enhance the compatibility of MOFs and polymers.
journal_name
Sci Advjournal_title
Science advancesauthors
Wu W,Su J,Jia M,Li Z,Liu G,Li Wdoi
10.1126/sciadv.aax7270subject
Has Abstractpub_date
2020-05-01 00:00:00pages
eaax7270issue
18issn
2375-2548pii
aax7270journal_volume
6pub_type
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