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Predominance of BDE-209 and other higher brominated diphenyl ethers in eggs of white stork (Ciconia ciconia) colonies from Spain.

Abstract：

:Polybrominated diphenyl ethers (PBDEs) are ubiquitous pollutants for which there is still a lack of knowledge about the environmental behavior and fate of the higher brominated congeners (octa- to deca-BDEs). In this study, the PBDE content and congener profiles in failed eggs from two colonies of white stork (Ciconia ciconia) in Spain were studied. The average total PBDE concentration was 1.64ng/g (wet weight, w.w.) for the rural colony and 9.08ng/g (w.w.) for the urban colony. Higher brominated BDEs dominated the congener profiles of both colonies. Of particular interest was the determination of BDE-209 as the dominant congener accounting for 44.1% and 38.6% of the total PBDE content in the rural and urban colonies, respectively. BDE-202, considered an indicator of BDE 209 debromination, was detected in 83% and all of the samples from rural and urban colonies, respectively. The observed congener profile in which BDE-207>BDE-208>BDE-206 does not correspond to any known technical PBDE mixture and is evidence for possible BDE-209 degradation.

journal_name

Environ Int

journal_title

Environment international

authors

Muñoz-Arnanz J,Sáez M,Aguirre JI,Hiraldo F,Baos R,Pacepavicius G,Alaee M,Jiménez B

doi

10.1016/j.envint.2010.11.013

subject

Has Abstract

pub_date

2011-04-01 00:00:00

pages

572-6

issue

3

eissn

0160-4120

issn

1873-6750

pii

S0160-4120(10)00243-6

journal_volume

37

pub_type

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