Thin molecular films of supramolecular porphyrins.

Abstract:

:A relevant series of symmetric supramolecular porphyrins has been obtained by attaching four [RuII(bipy)2Cl] groups to the pyridyl substituents of meso-tetra(4-pyridyl)porphyrin and its metallated derivatives. These compounds display a rich electrochemistry and versatile catalytic, electrocatalytic and photochemical properties, associated with the ruthenium-bipyridine and the porphyrin complexes. These properties can be transferred to the electrodes by attaching thin molecular films of the compounds, by dip-coating, electrostatic assembly or electropolymerization. In this way, the interesting properties of those supermolecules and supramolecular assemblies can be used to prepare molecular devices and sensors.

journal_name

An Acad Bras Cienc

authors

Araki K,Lima Sde S,Winnischofer H

doi

10.1590/s0001-37652000000100003

subject

Has Abstract

pub_date

2000-01-01 00:00:00

pages

27-32

issue

1

eissn

0001-3765

issn

1678-2690

pii

S0001-37652000000100003

journal_volume

72

pub_type

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