Synthesis, characterisation and antioxidant activity of luteolin-vanadium(II) complex.

Abstract:

:The complex formation between luteolin (L) and vanadium(IV) oxide sulphate monohydrate (VOSO4·H2O) was examined under UV-visible, infra-red spectroscopy, mass spectroscopy and NMR techniques. The spectroscopic data indicated that luteolin reacts with vanadium oxide cation (VO(+2)) through 4-carbonyl-5-hydroxy chelation site in the two luteolin molecule. The free radical antioxidant activity of the complex with respect to the parent molecule was evaluated using 1,1-diphenyl-2-picrylhydrazyl (DPPH), ferric reducing antioxidant power (FRAP) and 2,2'-azinobis 3-ethylbenzothiazoline-6-sulphonic acid diammonium salt (ABTS) methods. It was observed that the free radical scavenging activity and ferric ion reducing potential of luteolin was increased after the formation of complex with vanadium oxide (VO(+2)) cation.

journal_name

Food Chem

journal_title

Food chemistry

authors

Roy S,Mallick S,Chakraborty T,Ghosh N,Singh AK,Manna S,Majumdar S

doi

10.1016/j.foodchem.2014.10.141

subject

Has Abstract

pub_date

2015-04-15 00:00:00

pages

1172-8

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(14)01715-4

journal_volume

173

pub_type

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