Ordered structure and thermal property of acid-modified high-amylose rice starch.

Abstract:

:High-amylose cereal starch has a great benefit on human health. Acid modification is very helpful for application of high-amylose starch in food and non-food industries. In this study, the ordered structure of acid-modified high-amylose rice starch was investigated by GPC, HPAEC, (13)C CP/MAS NMR and XRD. Acid preferentially degraded the amylose, then A chain and short B chain of amylopectin. Relative double helix content and crystallinity both initially increased sharply and then progressively with acid hydrolysis. The relative crystallinity of starches obtained from (13)C CP/MAS NMR was higher than that from XRD. The onset gelatinisation temperature decreased, while the peak and conclusion temperatures increased with increasing hydrolysis time. The endothermic value initially increased and then decreased with acid hydrolysis. The swelling power decreased while solubility increased after acid hydrolysis. These results add to our understanding of the effect of acid hydrolysis on the high-amylose rice starch.

journal_name

Food Chem

journal_title

Food chemistry

authors

Man J,Qin F,Zhu L,Shi YC,Gu M,Liu Q,Wei C

doi

10.1016/j.foodchem.2012.04.100

subject

Has Abstract

pub_date

2012-10-15 00:00:00

pages

2242-8

issue

4

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(12)00763-7

journal_volume

134

pub_type

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