Electrochemical decolourisation of structurally different dyes.

Abstract:

:The electrochemical decolourisation of structurally different dyes (bromophenol blue, indigo, poly R-478, phenol red, methyl orange, fuchsin, methyl green and crystal violet) by means of the application of DC electric current was assessed. It was found that the electrochemical process allowed a colour removal of all dyes studied, although the decolourisation rate largely depended on the chemical structure of the different dyes. Nearly complete decolourisation was achieved for bromophenol blue followed by methyl orange and methyl green, whereas phenol red was hardly decolourised (30% in 60 min). In mixtures of two dyes, the decolourisation rate became similar for both dyes. However, the addition of a redox mediator, (Co(2+/3+)) clearly enhanced the degradation rate of all tested dyes, but the simplest dye molecules were attacked firstly, followed by dyes with more complex chemical structures. The results revealed the suitability of the process to effectively decolourise wastewaters from dyeing process.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Sanromán MA,Pazos M,Ricart MT,Cameselle C

doi

10.1016/j.chemosphere.2004.06.019

subject

Has Abstract

pub_date

2004-10-01 00:00:00

pages

233-9

issue

3

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(04)00472-2

journal_volume

57

pub_type

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