Anaerobic degradation of diethyl phthalate, di-n-butyl phthalate, and di-(2-ethylhexyl) phthalate from river sediment in Taiwan.

Abstract:

:We investigated anaerobic degradation rates for three phthalate esters (PAEs), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), and di-(2-ethylhexyl) phthalate (DEHP), from river sediment in Taiwan. The respective anaerobic degradation rate constants for DEP, DBP, and DEHP were observed as 0.045, 0.074, and 0.027 1/day, with respective half-lives of 15.4, 9.4, and 25.7 days under optimal conditions of 30 degrees C and pH7.0. Anaerobic degradation rates were enhanced by the addition of the surfactants brij 35 and triton N101 at a concentration of 1 critical micelle concentration (CMC), and by the addition of yeast extract. Degradation rates were inhibited by the addition of acetate, pyruvate, lactate, FeCl3, MnO2, NaCl, heavy metals, and nonylphenol. Our results indicate that methanogen, sulfate-reducing bacteria, and eubacteria are involved in the degradation of PAEs.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Chang BV,Liao CS,Yuan SY

doi

10.1016/j.chemosphere.2004.11.031

subject

Has Abstract

pub_date

2005-03-01 00:00:00

pages

1601-7

issue

11

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(04)01104-X

journal_volume

58

pub_type

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