Effect of hydrogen generated by dielectric barrier discharge of NH3 on selective non-catalytic reduction process.

Abstract:

:Plasma-assisted selective non-catalytic reduction (SNCR) has been investigated to clarify which species generated by the plasma play a crucial role in NO reduction. We find that the presence of O(2) is indispensable and only H(2) is observed to be a stable product by dielectric barrier discharge (DBD) of NH(3). As the extent of NH(3) decomposition by DBD increases, the commencement temperature of SNCR processes is lowered and the working temperature window is widened. This propensity may be attributed to the chemical reaction of H(2) with O(2) to generate OH and H radicals which make it possible to yield NH(2) radicals even at low temperature.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Byun Y,Ko KB,Cho M,Namkung W,Shin DN,Koh DJ

doi

10.1016/j.chemosphere.2009.01.040

subject

Has Abstract

pub_date

2009-05-01 00:00:00

pages

815-8

issue

6

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(09)00079-4

journal_volume

75

pub_type

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