Abstract：
:Lignin peroxidase (LiP) is excreted by certain lignin-degrading fungi, such as white rot fungus Phanerochaete chrysosporium, in natural environments and is thus widely present in the natural environment. We have found in our earlier studies that LiP mediates effective reactions of a few natural and synthetic estrogens to form oligomeric products via radical coupling. We in particular examined the identity and property of the products resulting from 17beta-estradiol (E2) in LiP-mediated oxidative coupling reactions, and the results suggest that such reactions hold great potential in water/wastewater treatment to remove E2 and estrogenicity. Herein, we report a further investigation to postulate possible reaction pathways of E2 with the assistance of ab initio molecular modeling and to more systematically examine the reaction behavior of E2 under sequenced reaction conditions and in systems containing natural organic matter (NOM) at different levels. Our molecular modeling suggested the coupling of E2 likely proceeded via covalent bonding between two E2 radicals at their unsubstituted carbons in phenolic rings. Results obtained from sequenced reagent feed experiments revealed that the coupling products tended to be consumed with increment enzyme treatments, suggesting that most E2 coupling products may still be LiP substrates that can undergo further coupling reactions under catalysis. Higher concentration of NOM present in the reaction system tended to reduce E2 transformation. NOM moieties seemed to couple to each other upon reaction with LiP, which was evidenced by the development of a characteristic absorbance band.
journal_name
Chemospherejournal_title
Chemosphereauthors
Mao L,Huang Q,Luo Q,Lu J,Yang X,Gao Sdoi
10.1016/j.chemosphere.2010.03.054subject
Has Abstractpub_date
2010-06-01 00:00:00pages
469-73issue
4eissn
0045-6535issn
1879-1298pii
S0045-6535(10)00368-1journal_volume
80pub_type
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