Abstract:
:Metal-organic frameworks (MOFs) have recently debuted as participants and solid supports in catalysts for environmental application in water treatment. Visible light active nanocomposites; ZnO/MIL-101(Fe); were synthesized via a hydrothermal method by loading ZnO; prepared by a green method; on a porous MIL-101(Fe) to be used as a heterogeneous catalyst for Rhodamine B dye (RhB) degradation as a model pollutant. The effect of adding acetic acid during the preparation of MIL-101(Fe) was studied; [A] used for the samples prepared by acetic acid. The prepared catalysts were characterized by XPS, XRD, zeta potential, TGA, FTIR, N2 adsorption-desorption measurements, SEM, EDX, elemental mapping, TEM, and UV-VIS diffuse reflectance spectroscopy. The loading of ZnO on MIL-101(Fe) decreased the band gap from 3.2 eV for ZnO to be 2.85 eV for ZnO/MIL-101(Fe)[A], this low band gap explaining the obtained high activity under visible light irradiation. The mechanism of the photocatalytic degradation of RhB was investigated by introducing different scavengers to compete for the possible reactive species involved in the degradation process. The trapping experiments indicated that h+ and •OH have a vital role in the RhB degradation. The reusability of MIL-101(Fe) was also investigated after three runs. Thus, the synthesized ZnO/MIL-101(Fe)[A] could be used as an alternative catalyst for the photocatalytic degradation of coloured wastewater as it can successfully degrade 97.1% of Rhodamine B (10 mg/L) with high reaction rate (k = 0.0339 min-1) under visible light irradiation for 300 min using 0.5 g/L of the catalyst. The as-prepared ZnO/MIL-101(Fe) and ZnO/MIL-101(Fe)[A] have competitive photocatalytic dye degradation activity.
journal_name
Environ Technoljournal_title
Environmental technologyauthors
Amdeha E,Mohamed RSdoi
10.1080/09593330.2019.1647290subject
Has Abstractpub_date
2019-08-11 00:00:00pages
1-18eissn
0959-3330issn
1479-487Xpub_type
杂志文章abstract::In this work, the mechanism of the Cr(III) sorption by Salvinia auriculata biosorbent was studied in two stages. To understand the influence of the sorption parameters on the Cr(III) uptake, preliminary tests were performed. First, S. auriculata biomass was separately treated with base and acid solutions. Second, acid...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2016.1234002
更新日期:2017-06-01 00:00:00
abstract::The demand for removal of refractory organic pollutants limits the application of microbial fuel cells. In this study, the synergistic effects of bioelectrochemical and photocatalysis methods were captured by constructing a biophoto anode from a combination of WO3/TiO2 and carbon felt. This biophoto electrode was able...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2019.1611936
更新日期:2020-11-01 00:00:00
abstract::An anaerobic membrane bioreactor (MBR) was operated for 367 days to treat domestic wastewater originating from the Sfax wastewater treatment plant. The results showed that the MBR was not very efficient because of the considerable fluctuations in the domestic wastewater composition and the presence of toxic compounds ...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330903100027
更新日期:2009-12-01 00:00:00
abstract::The aim of the study was to determine the biogas productivity from selected cultivars of sorghum (Sorghum bicolor Moench) and maize (Zea mays L.) depending on the dose of mineral fertilization with nitrogen. The topic is novelty in the northern Poland area due to the fact that this crop is not very widespread here. Th...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2019.1584251
更新日期:2020-09-01 00:00:00
abstract::Maturation ponds are excellent natural treatment systems for disinfecting domestic wastewater from pathogenic bacteria because of their great sunlight exposure through depth and high pH and dissolved oxygen values - all considered important factors. Escherichia coli (E. coli) removal is higher at closer to the surface...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2017.1310936
更新日期:2018-03-01 00:00:00
abstract::Aminophenols (AP) are synthetic intermediates in pharmaceutical, photographic and chemical dye industry. They can be released into the environment from wastewater and can react during water treatment processes. Therefore, it was interesting to study the oxidation of AP with chlorine and monochloramine in aqueous solut...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2015.1025859
更新日期:2015-01-01 00:00:00
abstract::The structure and physicochemical characteristics of weathered surfaces of marble in industrial environments can be attributed to the interconnected evolution of the processes taking place at the atmospheric environment--marble interface. The present work is an attempt to correlate the aerosols of a heavily polluted a...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593332208618236
更新日期:2001-06-01 00:00:00
abstract::Herbal Pharmaceutical wastewater was subjected to physico-chemical treatment using conventional coagulants individually and in combination with different anionic, cationic and nonionic polyelectrolytes. Results indicate cationic polyelectrolyte to be the best polymer. Individually Alum did not give good results but Al...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593332608618550
更新日期:2005-04-01 00:00:00
abstract::Trichosporon akiyoshidainum HP2023 is a basidiomycetous yeast isolated from Las Yungas rainforest (Tucumán, Argentina) and selected based on its outstanding textile-dye-decolorizing ability. In this work, the decolorization process was optimized using Reactive Black 5 as dye model. Lactose and urea were chosen as carb...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2017.1375024
更新日期:2018-12-01 00:00:00
abstract::Hospital wastewater contains a great variety of pharmaceutical compounds (PhCs), mainly due to excretion by patients. These PhCs, called emerging pollutants, are not fully eliminated in treatment plants, and are consequently detected in various environmental matrices, contributing to bacterial resistance and adverse e...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2016.1255262
更新日期:2017-09-01 00:00:00
abstract::This paper presented the influence of Al(III) on biodegradability, micromorphology, composition and functional groups characteristics of the biofilm extracellular polymeric substances (EPS) during different growth phases. The sequencing batch biofilm reactors were developed to cultivate biofilms under different Al(III...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2017.1378268
更新日期:2019-01-01 00:00:00
abstract::Anaerobic biofilm reactors have limitations in treating wastewaters with low organic substrate concentrations (COD value below 1000 mg/L) because the substrate cannot reach the microorganisms present in the interior part of the biogranules. Hence, the performance of these reactors is mainly influenced by the size of t...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2010.492400
更新日期:2011-01-01 00:00:00
abstract::This study presents the operation of a biotrickling filter when treating a monochlorobenzene (MCB) contaminated gaseous emission. Treatment dynamics were characterised by exposing the reactor to various MCB Organic Loads (OL). The use of different growth support materials, namely limestone, sand, ceramic and PVC pall-...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330309385699
更新日期:2003-12-01 00:00:00
abstract::Results from a lab-scale investigation of a hybrid in/out ultrafiltration and powdered activated carbon adsorption PAC/UF for removal of diclofenac (c0 = 5 mg/L) are presented. The efficiency of the process was compared for single pulse and continuous carbon dosing (PAC dose 5 mg/L) in dechlorinated tap water under fl...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2017.1354077
更新日期:2018-09-01 00:00:00
abstract::Micelle enhanced ultrafiltration (MEUF) is a surfactant-based membrane separation process that may be used to separate target ions from mixed metal aqueous solutions, such as leachates of coal ash and other geological wastewaters. The ability of MEUF to separate rare earth elements (REEs) was evaluated using sodium do...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2020.1812732
更新日期:2020-09-22 00:00:00
abstract::This study compares the operation of mesophilic and thermophilic anaerobic digestion of sewage sludge and their effects in uncontrolled phosphorus precipitation. The research has been carried out using a pilot plant consisting of two digesters of 1.6 m3 working volume, treating the mixed sludge of Alzira WWTP (Valenci...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2019.1681522
更新日期:2019-10-29 00:00:00
abstract::Microbial degradation of phenolic pollutants in industrial wastewater is dependent on enzymatic pathway comprising a cascade of phenol metabolizing enzymes. Phenol hydroxylase is the first enzyme of the pathway catalysing the initial attack on phenol in green algae Chlorella pyrenoidosa. The present work reports cost-...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2017.1349838
更新日期:2018-08-01 00:00:00
abstract::Textural, structural and morphological characteristics of the vitreous tuff were determined by means of several physicochemical techniques. The nitrogen adsorption isotherm at 77 K was fitted with the Brunnauer-Emmet-Teller model and together with the results of the average pore distribution showed a mesoporous materi...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2013.871352
更新日期:2014-05-01 00:00:00
abstract::The main aim of this work is to test the performance of red mud as a permeable reactive barrier (PRB) material for fluoride removal from water. Batch experiments were carried out to optimise the fluoride removal efficiency (RE) of activated red mud (ARM) based on four selected parameters, namely, the initial fluoride ...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2019.1609591
更新日期:2020-11-01 00:00:00
abstract::Seven household treatment technologies for the removal of arsenic (Alcan, BUET, DPHE/DANIDA, Garnet, Sono, Stevens, Tetrahedron) were each evaluated using water from 63 different tube wells taken from 3 different regions of Bangladesh. The technologies that were evaluated were chosen from those that appeared user frie...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593332508618444
更新日期:2002-12-01 00:00:00
abstract::This paper discusses decolorization and chemical oxygen demand (COD) abatement in olive mill wastewaters (OMW) by Phanerochaetae chrysosporium grown in static, suspended and immobilised cultures. When P chrysosporium is used in cultures, no decolorization of crude OMW is observed. Decolorization occurs only after remo...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593332708618749
更新日期:2006-12-01 00:00:00
abstract::Coagulation process is highly influenced by solution pH, floc breakage, and coagulant aid. In this work, two-stage addition of alum-based coagulants, polyaluminum chloride (PACl) and aluminum sulfate (Al2(SO4)3), was compared to their one-stage addition with the same total dosage. The dose ratio of primary and seconda...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2020.1762757
更新日期:2020-05-19 00:00:00
abstract::To enhance the capture of low-level indoor CO2, a commercial zeolite (13X) was modified with alkali and alkaline earth metals using an ion-exchange method. Although the calcium-impregnated sorbent (zeo-Ca) showed the largest adsorption capacity, with a strong binding force for carbon dioxide, its regeneration by heat ...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2011.551837
更新日期:2012-01-01 00:00:00
abstract::For potential use in air treatment by biofiltration, a new material composed of vermicompost and earthworms (Eisenia fetida) was tested for the removal of a volatile organic compound (VOC), toluene. The removal rate of toluene was measured during batch experiments in presence of vermicompost only, earthworms only and ...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2019.1595164
更新日期:2020-09-01 00:00:00
abstract::In the present study, the applicability of light-emitting diodes (LEDs) to a fibrous activated carbon (FAC)/titania (TiO2) composite used for the purification of gas-phase benzene, toluene, ethyl benzene and xylene was evaluated. The surface and morphological properties of the FAC and prepared FAC/TiO2 composite were ...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2012.743591
更新日期:2013-05-01 00:00:00
abstract::The effects of circulation reflux and micro-aeration on the performance of a modified anaerobic baffled reactor (ABR) for treatment of traditional Chinese medicine (TCM) wastewater were evaluated. The characteristics of anaerobic sludge and microbial community structure in the modified ABR were also investigated. The ...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2019.1604818
更新日期:2020-11-01 00:00:00
abstract::In this study, Fenton reagent has been adopted to oxidize and regenerate the resin based spherical activated carbon (SAC) adsorbed with toluene saturation. The effects of the mole ratio of Fe2+ and H2O2, the dosage of H2O2, pH value, temperature, regeneration time and the like on the regeneration rate of activated car...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2020.1797891
更新日期:2020-08-01 00:00:00
abstract::The potential for phytoremediation of high concentrations of petroleum hydrocarbons is poorly understood. This study examines variations in phytoremediation performance for a soil contaminated with diesel at 6400 mg TPH kg-1 dry mixture. Experiments on diesel-contaminated soil were conducted in cups using 200 g of soi...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593332208618301
更新日期:2001-02-01 00:00:00
abstract::Municipal and agricultural waste, and sludge from wastewater treatment represent a large source of pollution. Gaseous fuels can be produced from waste decomposition and then used to run internal combustion engines for power and heat generation. The present paper focuses on thermal efficiency and environmental performa...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330309385657
更新日期:2003-09-01 00:00:00
abstract::It is the priority to guarantee biosafety for drinking water treatment. The objective of this study was to evaluate the impact of widely applied conventional and ozone-biological activated carbon (O3-BAC) advanced treatment technology on biosafety of drinking water. The items, including assimilable organic carbon (AOC...
journal_title:Environmental technology
pub_type: 杂志文章
doi:10.1080/09593330.2017.1297850
更新日期:2018-01-01 00:00:00