Pollutant content in marine debris and characterization by thermal decomposition.

Abstract:

:Marine debris (MDs) produces a wide variety of negative environmental, economic, safety, health and cultural impacts. Most marine litter has a very low decomposition rate (plastics), leading to a gradual accumulation in the coastal and marine environment. Characterization of the MDs has been done in terms of their pollutant content: PAHs, ClBzs, ClPhs, BrPhs, PCDD/Fs and PCBs. The results show that MDs is not a very contaminated waste. Also, thermal decomposition of MDs materials has been studied in a thermobalance at different atmospheres and heating rates. Below 400-500K, the atmosphere does not affect the thermal degradation of the mentioned waste. However, at temperatures between 500 and 800K the presence of oxygen accelerates the decomposition. Also, a kinetic model is proposed for the combustion of the MDs, and the decomposition is compared with that of their main constituents, i.e., polyethylene (PE), polystyrene (PS), polypropylene (PP), nylon and polyethylene-terephthalate (PET).

journal_name

Mar Pollut Bull

authors

Iñiguez ME,Conesa JA,Fullana A

doi

10.1016/j.marpolbul.2017.02.022

subject

Has Abstract

pub_date

2017-04-15 00:00:00

pages

359-365

issue

1-2

eissn

0025-326X

issn

1879-3363

pii

S0025-326X(17)30137-6

journal_volume

117

pub_type

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