Abstract:
:Metal contaminants in soils can persist for millennia, causing lasting negative impacts on local ecosystems. Long-term contaminant bioavailability is related to soil pH and to the strength and stability of solid-phase associations. We combined physical density separation with synchrotron-based microspectroscopy to reduce solid-phase complexity and to study Zn speciation in field-contaminated soils. We also investigated Zn uptake in two Zn-hyperaccumulating ecotypes of (Ganges and Prayon). Soils were either moderately contaminated (500-800 mg Zn kg via contaminated biosolids application) or grossly enriched (26,000 mg Zn kg via geogenic enrichment). Soils were separated using sodium polytungstate into three fractions: light fraction (LF) (<1.6 g cm), medium fraction (MF) (1.6-2.8 g cm), and heavy fraction (HF) (>2.8 g cm). Approximately 45% of the total Zn was associated with MF in biosolids-contaminated soils. From these data, we infer redistribution to the MF after biosolids application because Zn in biosolids is principally associated with HF and LF. Our results suggest that increasing proportions of HF-associated Zn in soils may be related to greater relative Zn removal by Zn hyperaccumulating plants. Using density fractions enabled assessment of Zn speciation on a microscale despite incomplete fractionation. Analyzing both density fractions and whole soils revealed certain phases (e.g., ZnS, Zn coprecipitated with Fe oxides) that were not obvious in all analyses, indicating multiple views of the same soils enable a more complete understanding of Zn speciation.
journal_name
J Environ Qualjournal_title
Journal of environmental qualityauthors
Rosenfeld CE,Chaney RL,Tappero RV,Martínez CEdoi
10.2134/jeq2016.05.0184subject
Has Abstractpub_date
2017-03-01 00:00:00pages
373-383issue
2eissn
0047-2425issn
1537-2537journal_volume
46pub_type
杂志文章abstract::The New York Phosphorus Index (NY-PI) was introduced in 2001 after the release of the state's first Concentrated Animal Feeding Operation (CAFO) Permit that required a nutrient management plan developed in accordance with NRCS standards. The stakeholder-based approach to development of the NY-PI, combined with a requi...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2016.05.0185
更新日期:2017-11-01 00:00:00
abstract::In their natural state, river floodplains are heterogeneous and dynamic ecosystems that may retain and remove large quantities of nitrogen from surface waters. We compared the soil nitrogen dynamics in different types of habitat patches in a restored and a channelized section of a Thur River floodplain (northeast Swit...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2012.0059
更新日期:2012-11-01 00:00:00
abstract::Herbicides may leach from agricultural fields into ground water feeding adjacent wetlands. However, only little is known of the fate of herbicides in wetland areas. The purpose of the study was to examine the potential of a riparian fen to mineralize herbides that could leach from an adjacent catchment area. Slurries ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2001.30124x
更新日期:2001-01-01 00:00:00
abstract::Increasing chloride (Cl) concentration in soil solution has been shown to increase cadmium (Cd) concentration in soil solution and Cd uptake by plants, when grown in phosphate fertilizer- or biosolid-amended soils. However, previous experiments did not distinguish between the effect of Cl on biosolid-borne Cd compared...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2004.4960
更新日期:2004-03-01 00:00:00
abstract::Perchlorate (ClO4-) contamination of ground water and surface water is a widespread problem, particularly in the western United States. This study examined the effect of biodegradation on perchlorate fate and transport in soils. Solute transport experiments were conducted on two surface soils. Pulses of solution conta...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2003.4000
更新日期:2003-01-01 00:00:00
abstract::Phosphorus (P) loss from agricultural fields can contribute to water quality degradation. The current New York P index (NY-PI) scores fields on the basis of P sources and field characteristics that reflect risk of P transport (a source × transport approach). Recently, a transport × best management practice (BMP) appro...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2019.01.0010
更新日期:2019-07-01 00:00:00
abstract::With increasing concern over potential polltion from farm wastes, there is a need for rapid and robust methods that can analyze livestock manure nutrient content. The near infrared spectroscopy (NIRS) method was used to determine nutrient content in diverse poultry manure samples (n=91). Various standard preprocessing...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2009.0449
更新日期:2010-09-01 00:00:00
abstract::To control ammonia (NH(3)) volatilization from the dairy cattle (Bos taurus) manure composting process, a compost pile was covered with mature compost and the gas emissions evaluated using the dynamic chamber system. The peak of NH(3) volatilization observed immediately after piling up of the compost was reduced from ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2008.0083
更新日期:2009-02-06 00:00:00
abstract::The objective of the Parafield Aquifer Storage Transfer and Recovery research project in South Australia is to determine whether stormwater from an urban catchment that is treated in a constructed wetland and stored in an initially brackish aquifer before recovery can meet potable water standards. The water produced b...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2010.0078
更新日期:2010-11-01 00:00:00
abstract::The variations in the quality of floodwaters from the upper Leichhardt River catchment (1113 km), Mount Isa, in northwest Queensland, Australia, were examined to better understand the impact of urban, mining, and industrial activity on receiving waters. Water sampling was conducted during the 2006-2007 wet season and ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2010.0349
更新日期:2013-03-01 00:00:00
abstract::In confined animal feeding operations, liquid manure systems present special handling and storage challenges because of the large volume of diluted wastes. Water treatment polymers and mineral phosphorus (P) immobilizing chemicals [AI2(SO4)3 x 18H2O, FeCl3-6H2O, and Class C fly ash] were used to determine particulate ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2002.1388
更新日期:2002-07-01 00:00:00
abstract::In many regions, conservation tillage has replaced conventional tilling practices to reduce soil erosion, improve water conservation, and increase soil organic matter. However, tillage can have marked effects on soil properties, specifically nutrient redistribution or stratification in the soil profile. The objective ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2009.0491
更新日期:2010-09-01 00:00:00
abstract::Coastal aquatic ecosystems are increasingly affected by diffuse source nutrient water pollution from agricultural activities in coastal catchments, even though these ecosystems are important from a social, environmental and economic perspective. To warrant sustainable economic development of coastal regions, we need t...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2011.0400
更新日期:2014-01-01 00:00:00
abstract::Recent strategies to reduce elevated nitrate concentrations employ metallic Fe0 as a reductant. Secondary products of Fe0 corrosion include magnetite (Fe3O4), green rust [Fe6(OH)12SO4], and wüstite [FeO(s)]. To our knowledge, no studies have been reported on the reactivity of NO3- with FeO(s). This project was initiat...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2004.0459
更新日期:2005-07-05 00:00:00
abstract::Constructed wetland treatment systems are used to remove selenium (Se) from flue-gas desulfurization (FGD) wastewater (WW). However, direct confirmation of the mechanism responsible for FGD WW Se retention in soil is lacking. A laboratory-based soil column study was performed to develop an evidence-based mechanism of ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2016.09.0335
更新日期:2017-03-01 00:00:00
abstract::This study was undertaken to determine the fate of As, Mo, and V (trace elements, TEs) in the sediments of a constructed wetland in use for the remediation of potentially toxic trace element-contaminated agricultural drainwater. After three years of wetland operation, sediment cores were collected to determine changes...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2003.2428
更新日期:2003-11-01 00:00:00
abstract::We examined constraints on soil CO2 respiration in natural oak woodlands, and adjacent vineyards that were converted approximately 30 yr ago from oak woodlands, in the Oakville Region of Napa Valley, California. All sites were located on the same soil type, a Bale (variant) gravelly loam (fine-loamy, mixed, superactiv...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2005.0155
更新日期:2006-07-06 00:00:00
abstract::High grazing pressure can lead to soil erosion in pastures, causing increased sediment delivery to waterways. The objectives of this research were to evaluate the impact of grazing management and buffer strips on soil erosion by assessing soil physical properties, hydrology, and sediment loads from pastures fertilized...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2016.09.0378
更新日期:2017-03-01 00:00:00
abstract::Urban landscapes contain a mix of land-use types with different patterns of nitrogen (N) cycling and export. We measured nitrate (NO(3)(-)) leaching and soil:atmosphere nitrous oxide (N(2)O) flux in four urban grassland and eight forested long-term study plots in the Baltimore, Maryland metropolitan area. We evaluated...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2008.0521
更新日期:2009-07-23 00:00:00
abstract::Patch burning can be a potential management tool to create grassland heterogeneity and enhance forage productivity and plant biodiversity, but its impacts on soil and environment have not been widely documented. In summer 2013, we studied the effect of time after patch burning (4 mo after burning [recently burned patc...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2014.12.0523
更新日期:2015-05-01 00:00:00
abstract::Due to its resistance to many wastewater treatment processes, the antiepileptic drug carbamazepine (CBZ) is routinely found in wastewater effluent. Wastewater irrigation is an alternative to stream discharge of wastewater effluent, which utilizes the soil as a tertiary filter to remove excess nutrients and has the pot...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2011.0193
更新日期:2012-07-01 00:00:00
abstract::The objectives of this research were to evaluate nitrate N (NO³-N) leaching and turf response to nitrogen rate (NR) and irrigation regime (IR) in 'Floratam' St. Augustinegrass ( [Walt.] Kuntze.) and 'Empire' zoysiagrass ( Steud). The research was conducted in Citra, FL, from 2005 through 2007. Nitrogen (N) was applied...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2011.0183
更新日期:2012-05-01 00:00:00
abstract::Conservation tillage practices have become increasingly common in recent years to reduce soil erosion, improve water conservation, and increase soil organic matter. Research suggests that conservation tillage can stratify soil test phosphorus (P), but little is known about the effects on soil organic P. This study was...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2013.10.0424
更新日期:2014-07-01 00:00:00
abstract::Vegetation that develops spontaneously on metal-contaminated soils presents an opportunity to evaluate both metal bioavailability and the risks posed to biota. The behavior of Cd and Zn in the species of a spontaneously developed woodland, colonizing a canal embankment, has been investigated. Nitric-acid-extractable m...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2006.0218
更新日期:2007-06-27 00:00:00
abstract::Golf courses require extensive use of inputs to meet the needs of playability and aesthetics. The impact of these inputs on soil biological health is largely unknown. Two field trials were conducted at a golf course in Georgia to evaluate short-term effects of wetting agents (Cascade Plus and Duplex [C+D], Revolution ...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.1002/jeq2.20080
更新日期:2020-07-01 00:00:00
abstract::Phosphogypsum (PG), a by-product of the phosphate fertilizer industry, reduces N losses when added to composting livestock manure, but its impact on greenhouse gas emissions is unclear. The objective of this research was to assess the effects of PG addition on greenhouse gas emissions during cattle feedlot manure comp...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2004.0388
更新日期:2005-04-20 00:00:00
abstract::Antibiotics may appear in the environment when manure, sewage sludge, and other organic amendments are added to soils. There is concern that the presence of antibiotics in soils may lead to the development of antibiotic-resistant bacteria which may spread to the rest of the environment. This paper aims at evaluating t...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2005.0355
更新日期:2006-05-31 00:00:00
abstract::The management of artificially drained organic soils is a very important issue, since the accelerated mineralization and sometimes peat fires alter physical and chemical properties of soils and the availability of plant nutrients. This study was performed to determine relatively short- and long-term effects of peat fi...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2005.0170
更新日期:2006-04-03 00:00:00
abstract::Understanding temporal and spatial distributions of naturally occurring total organic carbon (TOC) in sediments is critical because TOC is an important feature of surface water quality. This study investigated temporal and spatial distributions of sediment TOC and its relationships to sediment contaminants in the Ceda...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2005.0221
更新日期:2006-01-03 00:00:00
abstract::Knowledge of pesticide distribution and persistence in nursery recycling pond water and sediment is critical for preventing phytotoxicity of pesticides during water reuse and to assess their impacts to the environment. In this study, sorption and degradation of four commonly used pesticides (diazinon, chlorpyrifos, ch...
journal_title:Journal of environmental quality
pub_type: 杂志文章
doi:10.2134/jeq2006.0123
更新日期:2006-08-09 00:00:00