Abstract:
:Deacetylation of enynyl acetates under basic conditions allows convenient access to reactive allenyl ketones, which can then undergo 1,4-addition of nucleophiles to furnish β,γ-unsaturated ketones. Benzofuran and indole derivatives have also been obtained from enynyl acetates with an o-hetero-atom-substituted aryl group via intramolecular 1,4-addition.
journal_name
Chem Pharm Bull (Tokyo)journal_title
Chemical & pharmaceutical bulletinauthors
Okamoto N,Sueda T,Yanada Rdoi
10.1248/cpb.c16-00170subject
Has Abstractpub_date
2016-01-01 00:00:00pages
941-6issue
7eissn
0009-2363issn
1347-5223journal_volume
64pub_type
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