Abstract：
:Antibiotics and heavy metals often coexist in polluted environment, and the harm of combined pollution is greater than that of single pollution. In this study, a series of graphene supported p-n heterojunction rGO@Cu2O/BiVO4 composites are synthesized with different Cu2O doping for simultaneous detoxification of Cr(VI) and antibiotics. The obtained photocatalysts (rGO@Cu2O/BiVO4) with proper loading amount of Cu2O shows the a high photocatalytic degradation activity for simultaneously efficient Cr(VI) reduction and sulfamethoxazole (SMZ) oxidation under LED light at neutral pH. The Cr(VI) was completely transformed to Cr(III) rather than simply Cr(VI) adsorbed on the surface of rGO@Cu2O/BiVO4. The photocatalytic activity of composites can be attributed to excellent electrical conductivity of rGO and the p-n heterojunction between Cu2O and BiVO4, which promotes the spatial separation of photogenerated charges at the heterojunction boundary and inhibits of the photogenerated h+ and e- recombination. It's confirmed that h+, O2- and OH are the main reactive species for the photocatalytic SMZ oxidation, and the most important reactive species is h+. Finally, the tentative degradation pathways of SMZ are proposed based on the liquid chromatography-triple quadrupole mass spectrometry analysis. This work provides an effective approach for the treatment of water that contains SMZ and Cr(VI) under LED light.
journal_name
Chemospherejournal_title
Chemosphereauthors
Huang Z,Dai X,Huang Z,Wang T,Cui L,Ye J,Wu Pdoi
10.1016/j.chemosphere.2019.01.087subject
Has Abstractpub_date
2019-04-01 00:00:00pages
824-833eissn
0045-6535issn
1879-1298pii
S0045-6535(19)30093-1journal_volume
221pub_type
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