Electrospun metal-organic frameworks with polyacrylonitrile as precursors to hierarchical porous carbon and composite nanofibers for adsorption and catalysis.

Abstract:

:A facile and effective method has been developed to prepare hierarchical porous carbon nanofibers (PCNFs), carbon nanofibers supported nickel nanoparticles (PCNFs-Ni) and carbon nanofibers encapsulating gold nanoparticles (PCNFs-Au). PCNFs or PCNFs-Au were obtained by embedding metal-organic frameworks (e.g. ZIF-8 or ZIF-8-Au) into polyacrylonitrile via electrospinning and subsequent carbonization. In addition, PCNFs-Ni were obtained by impregnating PAN/ZIF-8 nanofibers in Ni(NO3)2·6H2O followed by carbonization. Both PCNF and PCNF-Ni exhibited excellent adsorption activities for methylene blue (MB) and congo red (CR). Especially, PCNF-Ni could be removed and separated via a magnet. PCNFs-Au showed excellent catalytic properties in the reduction reaction of 4-nitrophenol (4-NP).

journal_name

Chemosphere

journal_title

Chemosphere

authors

Wang J,Cai C,Zhang Z,Li C,Liu R

doi

10.1016/j.chemosphere.2019.124833

subject

Has Abstract

pub_date

2020-01-01 00:00:00

pages

124833

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(19)32072-7

journal_volume

239

pub_type

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