Ozone facilitated dechlorination of 2-chloroethanol and impact of organic solvents and activated charcoal.

Abstract:

:The ozone-initiated oxidation of 2-chloroethanol was followed by monitoring the consumption of the halogenated organic substrate. Gas chromatographic analysis of the ozonated products showed an increase in conversion from about 1 % after 3 h of ozone treatment to about 22 % after 12 h. The yields of major ozonated products identified and quantified namely acetaldehyde, acetic acid, and chloride ion increased proportionately as a function of ozone treatment time. The percent conversion of 2-chloroethanol in the presence of acetic acid or ethyl acetate were found to be higher than those under solvent-free conditions with similar products obtained. The use of activated charcoal during the ozonolyis of 2-chloroethanol showed a significant increase in the percent conversion of the substrate compared to solvent free ozonation. Based on the experimental findings, the overall mechanism for the reaction between 2-chloroethanol and ozone is described.

journal_name

Environ Monit Assess

authors

Gounden AN,Jonnalagadda SB

doi

10.1007/s10661-013-3169-4

subject

Has Abstract

pub_date

2013-10-01 00:00:00

pages

8227-37

issue

10

eissn

0167-6369

issn

1573-2959

journal_volume

185

pub_type

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