Adsorption and corrosion inhibition behaviour of new theophylline-triazole-based derivatives for steel in acidic medium.

Abstract:

:The design and synthesis of a series of theophylline derivatives containing 1,2,3-triazole moieties are presented. The corrosion inhibition activities of these new triazole-theophylline compounds were evaluated by studying the corrosion of API 5 L X52 steel in 1 M HCl medium. The results showed that an increase in the concentration of the theophylline-triazole derivatives also increases the charge transference resistance (Rct) value, enhancing inhibition efficiency and decreasing the corrosion process. The electrochemical impedance spectroscopy under static conditions studies revealed that the best inhibition efficiencies (approx. 90%) at 50 ppm are presented by the all-substituted compounds. According to the Langmuir isotherm, the compounds 4 and 5 analysed exhibit physisorption-chemisorption process, with exception of the hydrogen 3, bromo 6 and iodo 7 substituted compounds, which exhibit chemisorption process. The corrosion when submerging a steel bar in 1 M HCl was studied using SEM-EDS. This experiment showed that the corrosion process decreases considerably in the presence of 50 ppm of the organic inhibitors. Finally, the theoretical study showed a correlation between EHOMO, hardness (η), electrophilicity (W), atomic charge and the inhibition efficiency in which the iodo 7 substituted compound presents the best inhibitor behaviour.

journal_name

R Soc Open Sci

authors

Espinoza-Vázquez A,Rodríguez-Gómez FJ,Martínez-Cruz IK,Ángeles-Beltrán D,Negrón-Silva GE,Palomar-Pardavé M,Romero LL,Pérez-Martínez D,Navarrete-López AM

doi

10.1098/rsos.181738

subject

Has Abstract

pub_date

2019-03-27 00:00:00

pages

181738

issue

3

issn

2054-5703

pii

rsos181738

journal_volume

6

pub_type

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